A Study for Coating Boron Particles with Two-Solvent Method and its Process Parameters

Journal of Propulsion Technology ›› 2013, Vol. 34 ›› Issue (7): 984-990.

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A Study for Coating Boron Particles with Two-Solvent Method and its Process Parameters

State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China;State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China;State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China;State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China;State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China;State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China

Published:2021-08-15

双溶剂法硼包覆工艺及其工艺参数研究

席剑飞,刘建忠,胡友瑞,汪洋,张彦威,周俊虎

浙江大学能源清洁利用国家重点实验室,浙江杭州 310027;浙江大学能源清洁利用国家重点实验室,浙江杭州 310027;浙江大学能源清洁利用国家重点实验室,浙江杭州 310027;浙江大学能源清洁利用国家重点实验室,浙江杭州 310027;浙江大学能源清洁利用国家重点实验室,浙江杭州 310027;浙江大学能源清洁利用国家重点实验室,浙江杭州 310027

作者简介:席剑飞(1989—),男,博士生,研究领域为含能材料。E-mail:jianfeixi@126.com 通讯作者:刘建忠(1965—),男,教授,博导,研究领域为新能源与可再生能源。 E-mail:jzliu@zju.edu.cn
基金资助:
国家自然科学基金(109203-N11119)。

Abstract

Abstract: Because of the shortcoming of recrystallization method, a new way named two-solvent method for coating boron particles was proposed. The PH-method was used to verify boron coating effect. The effects of ultrasonic mixing time, evaporation temperature and stirring speed on coating effect were studied through orthogonal experiment. The results show that two-solvent method is superior to recrystallization method for coating boron particles. The optimal value of ultrasonic mixing time is 10min. Using ultrasonic mixing can improve coating effect effectively. The optimal value of evaporation temperature is 350℃. Increasing evaporation temperature is beneficial to improving coating effect, but the promotion effect decreases with increasing evaporation temperature. The optimal value of stirring speed is 200r/min.If the stirring speed is too slow, it cannot maintain the uniform dispersion of boron particles in the solution which goes against the coating effect. Meanwhile, if the stirring speed is too high, the coating agent on the boron particles will exfoliate because of shear stress. 

Key words: Two-solvent method; Boron; Coating; Orthogonal experiment; Process parameters

摘要： 针对重结晶法硼包覆工艺的不足,采用了双溶剂法对硼颗粒进行包覆。应用pH法对包覆效果进行验证。设计正交实验研究了超声波混合时间、蒸发温度和搅拌速度这三种因素对双溶剂法包覆效果的影响。试验结果表明:双溶剂法的包覆效果要优于重结晶法；超声波混合时间的最优水平为10min,使用超声波混合可以有效地提高双溶剂法包覆效果；蒸发温度的最优水平为350℃,提高蒸发温度有利于促进包覆效果,但温度越高时,提高温度对包覆效果的促进作用将减弱；搅拌速度的最优水平为200r/min,一定的搅拌速度可以维持硼在溶液中的均匀分散,有利于硼颗粒的包覆,但搅拌速度过快又会使已经包覆在硼颗粒表面的LiF在剪切力的作用下重新从硼表面脱落,降低了包覆效果。 

关键词: 双溶剂法;硼;包覆;正交试验;工艺参数 

XI Jian-fei, LIU Jian-zhong, HU You-rui, WANG Yang, ZHANG Yan-wei, ZHOU Jun-hu. A Study for Coating Boron Particles with Two-Solvent Method and its Process Parameters[J]. Journal of Propulsion Technology, 2013, 34(7): 984-990.

席剑飞,刘建忠,胡友瑞,汪洋,张彦威,周俊虎. 双溶剂法硼包覆工艺及其工艺参数研究[J]. 推进技术, 2013, 34(7): 984-990.

References

[1] Lima R J P, Dubois C, Mader O, et al.Boron Nanoparticle-Rich Fuels for Gas Generators and Propellants[J].International Journal of Energetic Materials and Chemical Propulsion, 2010,9(5):437-446.
[2] Van Devener B, Perez J P L, Jankovich J, et al.Oxide-Free, Catalyst-Coated, Fuel-Soluble, Air-Stable Boron Nanopowders as Combined Combustion Catalyst and High Energy Density Fuel[J].Energy & Fuels, 2009,3(6):111-120.
[3] Young G, Sullivan K, Zachariah M R, et al.Combustion Characteristics of Boron Nanoparticles[J].Combustion and Flame, 2009,6(2):322-333.
[4] Yeh C L, Kuo K K.Ignition and Combustion of Boron Particles[J].Progress in Energy and Combustion Science, 1996,2(6):511-541.
[5] Ulas A, Kuo K K, Gotzmer C.Ignition and Combustion of Boron Particles in Fluorine-Containing Environments[J].Combustion and Flame, 2001,7(2):1935-1957.
[6] 范红杰, 王宁飞, 樊学忠, 等.含硼富燃料推进剂点火特性[J].推进技术, 2008,9(1):102-104.(FAN Hong-jie, WANG Ning-fei, FAN Xue-zhong, et al.Ignition Characteristics of Boron-Based Fuel-Rich Propellants[J].Journal of Propulsion Technology, 2008,9(1):102-104.)
[7] 赵孝彬, 张小平.硼粒子包覆工艺及对硼的表面和燃烧特性的影响[J].固体火箭技术, 1998,1(1):35-38.
[8] Liu T K, Luh S P, Perng H C.Effect of Boron Particle Surface Coating on Combustion of Solid Propellants for Ducted Rockets[J].Propellants, Explosives, Pyrotechnics, 1991,6(4):156-166.
[9] T JC, B JD.Coating of Boron Particles[P].US:4915753,1990.
[10] Yeh C L, Hsieh W H, Felder W.Ignition and Combustion of Mg-Coated and Uncoated Boron Particles[J].International Journal of Energetic Materials and Chemical Propulsion.1996,3(1), 327-341.
[11] King M K, Komar J, Fry R S.Fuel-Rich Solid Propellant Boron Combustion[R].AIAA AD-A 148522,4.
[12] 高东磊, 张炜, 朱慧, 等.包覆及团聚对硼燃烧的影响[J].含能材料, 2007,5(4):378-381.
[13] Liu S X, Yue B, Jiao K, et al.Template Synthesis of One-Dimensional Nanostructured Spinel Zinc Ferrite[J].Materials Letters, 2006,0(2):154-158.
[14] 裴素硼, 周义峰, 岳斌, 等.双溶剂浸渍法制备VO_x/MCF催化剂及丙烷选择氧化[J].分子催化, 2012,6(2):127-134.
[15] 张教强, 庞维强, 苏力宏, 等.超细硼粉的HTPB包覆[J].化工进展, 2007,6(11):164-171.
[16] 苏卫国, 张伟.利用白刺果实提取红色素及稳定性研究[J].天津农学院学报, 2002,9(4):5-11.

A Study for Coating Boron Particles with Two-Solvent Method and its Process Parameters

双溶剂法硼包覆工艺及其工艺参数研究

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