船舶柴油机黑炭排放研究现状与展望

doi:10.13675/j.cnki.tjjs.200313

推进技术 ›› 2020, Vol. 41 ›› Issue (11): 2427-2437.DOI: 10.13675/j.cnki.tjjs.200313

船舶柴油机黑炭排放研究现状与展望

吴刚^1,2，姜浩¹，李铁¹，依平¹，王腾飞¹

1.上海交通大学海洋工程国家重点实验室，上海 200240;2.上海海事大学商船学院，上海 201306

出版日期:2020-11-15 发布日期:2020-11-15
作者简介:吴　刚，博士后，讲师，研究领域为清洁能源应用与内燃机排放控制。E-mail：wugang@shmtu.edu.cn
基金资助:
国家自然科学基金面上项目（51776125）。

Research Prospect and Advancement of Black Carbon Emissions from Marine Diesel Engines

1.State Key Laboratory of Ocean Engineering，Shanghai Jiaotong University，Shanghai 200240，China;2.Merchant Marine College，Shanghai Maritime University，Shanghai 201306，China

Online:2020-11-15 Published:2020-11-15

摘要/Abstract

摘要： 为进一步加强对船舶柴油机黑炭排放生成机理和特性的理解，探索有效的黑炭检测方法和排放控制技术，本文回顾有关船舶排放政策、黑炭定义、生成机理、理化特性、采样和测试以及控制技术等研究进展。指出加强包括火焰内颗粒形成与氧化机制以及润滑油的影响等船舶黑炭排放生成机理研究的必要性。论述船舶黑炭颗粒微观形貌、纳观结构、表面官能团、氧化活性、粒径尺寸、化学成分、元素组成等理化特性及影响。归纳黑炭排放测试与控制技术，建议结合多种检测方法，解决黑炭测试结果的不确定性问题。提倡借鉴车用柴油机成功经验，促进燃料、燃烧和尾气后处理技术的协同进步，实现船舶柴油机黑炭排放的有效控制。

关键词: 船舶柴油机;黑炭;排放;理化特性;测试技术;控制技术

Abstract: To further strengthen the understanding of generation mechanism and characteristics of black carbon emitted from marine diesel engines and to explore related measurement and emission control technologies effectively， a review about emission policy related to ships， black carbon（BC） definition， formation mechanism， physical and chemical characteristics， sampling and measuring method， control measures was reported. It was first suggested to strengthen investigation on soot formation mechanism including formation and oxidation in flame and influence of lubricating oil. Additionally， characteristics of BC were discussed and analyzed， including microscopic aggregate morphology， nanostructure characteristics， surface functional groups， oxidation activity， particle size and composition. On this basis， it summarized measurement technology and control technology and suggested the combination of varieties of detection to solve the uncertainty of BC measurement. Summarized， it is advocated to learn from the successful experience of automotive diesel engines， by promoting the coordinated development of fuel， combustion and after-treatment devices， to reduce black carbon emissions from marine diesel engines.

Key words: Marine diesel engine;Black carbon;Emission;Physical and chemical characteristics;Measurement technology;Control technology

吴刚，姜浩，李铁，依平，王腾飞. 船舶柴油机黑炭排放研究现状与展望[J]. 推进技术, 2020, 41(11): 2427-2437.

WU Gang^1,2, JIANG Hao¹, LI Tie¹, YI Ping¹, WANG Teng-fei¹. Research Prospect and Advancement of Black Carbon Emissions from Marine Diesel Engines[J]. Journal of Propulsion Technology, 2020, 41(11): 2427-2437.

参考文献

[1] Bond T C， Doherty S J， Fahey D W， et al. Bounding the Role of Black Carbon in the Climate System： A Scientific Assessment［J］. Journal of Geophysical Research： Atmospheres， 2013， 118（11）： 5380-5552.
[2] Comer B. Black Carbon Emissions and Fuel Use in Global Shipping［R］. Washington D C： International Council on Clean Transportation， 2017.
[3] Corbett J， Winebrake J， Green H， al et， Mortality from Ship Emissions： A Global Assessment［J］. Environmental Science & Technology， 2007， 41（24）： 8512-8518.
[4] EPA M. Report to Congress on Black Carbon［R］. Washington D C： Department of the Interior， and Related Agencies， 2012.
[5] GB15097-2016，船舶发动机排气污染物排放限值及测量方法（中国第一、二阶段）［S］.
[6] Di Natale F， Carotenuto C. Particulate Matter in Marine Diesel Engines Exhausts： Emissions and Control Strategies［J］. Transportation Research Part D： Transport and Environment， 2015， 40： 166-191.
[7] Maricq M M. Examining the Relationship Between Black Carbon and Soot in Flames and Engine Exhaust［J］. Aerosol Science and Technology， 2014， 48（6）： 620-629.
[8] Kholghy M. Detailed and Fundamental Modeling of Soot Formation［EB/OL］. https：//thomsonlab.mie.utoronto.ca/detailed-and-fundamental-modeling-of-soot-formation/，2020-09-11.
[9] Reilly P T A， Gieray R A， Whitten W B， et al. Direct Observation of the Evolution of the Soot Carbonization Process in an Acetylene Diffusion Flame Via Real-Time Aerosol Mass Spectrometry［J］. Combustion and Flame， 2000， 122（1-2）： 90-104.
[10] Kholghy R， Veshkini A， Thomson J. The Core-Shell Internal Nanostructure of Soot： A Criterion to Model Soot Maturity［J］. Carbon， 2016， 100： 508-536.
[11] Johansson K O， Head-Gordon M P， Schrader P E， et al. Resonance-Stabilized Hydrocarbon-Radical Chain Reactions May Explain Soot Inception and Growth［J］. Science， 2018， 361： 997-1000.
[12] Dec J E. A Conceptual Model of Di Diesel Combustion Based on Laser-Sheet Imaging［R］. SAE TP-970873， 1997.
[13] Black F. High Methodology for Determining Particulate and Gaseous Diesel Hydrocarbon Emissions［R］. SAE TP-790422， 1979.
[14] Hilden D L， Mayer W J. The Contribution of Engine Oil to Particulate Exhaust Emissions from Light-Duty， Diesel-Powered Vehicles［R］. SAE TP-841395， 1984.
[15] Buchholz B A， Dibble R W， Rich D， et al. Quantifying the Contribution of Lubrication Oil Carbon to Particulate Emissions from a Diesel Engine［R］. SAE TP-2003-01-1987.
[16] Jones H， Mctaggart G， Rogak S. Source Apportionment of Particulate Matter from a Diesel Pilot-Ignited Natural Gas Fuelled Heavy Duty Di Engine［R］. SAE TP-2005-01-2149.
[17] Lieke K I， Rosen?rn T， Pedersen J， et al. Micro-and Nanostructural Characteristics of Particles Before and After an Exhaust Gas Recirculation System Scrubber［J］. Aerosol Science and Technology， 2013， 47（9）： 1038-1046.
[18] Jiang H， Wu G， Li T， et al. Characteristics of Particulate Matter Emissions from a Low-Speed Marine Diesel Engine at Various Loads［J］. Environmental Science & Technology， 2019， 53（19）： 11552-11559.
[19] Lee K O， Cole R， Sekar R， et al. Morphological Investigation of the Microstructure， Dimensions， and Fractal Geometry of Diesel Particulates［J］. Proceedings of the Combustion Institute， 2002， 29（1）： 647-653.
[20] Jiang H， Li T， Wang Y， et al. The Evolution of Soot Morphology and Nanostructure Along Axial Direction in Diesel Spray Jet Flames［J］. Combustion & Flame， 2019， 199： 204-212.
[21] Jiang H， Li T， Wang Y， et al. Morphology and Nano-Structure Analysis of Soot Particles Sampled from High Pressure Diesel Jet Flames under Diesel-Like Conditions［J］. Measurement Science & Technology， 2018， 29（4）.
[22] Pahalagedara L， Sharma H， Kuo C H， et al. Structure and Oxidation Activity Correlations for Carbon Blacks and Diesel Soot［J］. Energy Fuels， 2012， 26： 6757-6764.
[23] Lu T， Cheung C S， Huang Z. Effects of Engine Operating Conditions on the Size and Nanostructure of Diesel Particles［J］. Journal of Aerosol Science， 2012， 47： 27-38.
[24] Wang L， Song C， Song J， et al. Aliphatic C-H and Oxygenated Surface Functional Groups of Diesel In-Cylinder Soot： Characterizations and Impact on Soot Oxidation Behavior［J］. Proceedings of the Combustion Institute， 2013， 34（2）： 3099-3106.
[25] 贺鹏飞，李铁，姜浩，等. 柴油喷雾火焰中碳烟颗粒形貌及纳观结构特性［J］. 内燃机学报， 2019， 37（3）： 251-256.
[26] Kittelson D B. Engines and Nanoparticles： a Review［J］. Journal of Aerosol Science， 1998， 29（5-6）： 575-588.
[27] Kasper A， Aufdenblatten S， Forss A， et al. Particulate Emissions from a Low-Speed Marine Diesel Engine［J］. Aerosol Science and Technology， 2007， 41 （1）： 24-32.
[28] Ashraful A M， Masjuki H H， Kalam M A. Particulate Matter， Carbon Emissions and Elemental Compositions from a Diesel Engine Exhaust Fuelled with Diesel-Biodiesel Blends［J］. Atmospheric Environment， 2015， 120： 463-474.
[29] Wu D， Zhang F， Lou W， et al. Chemical Characterization and Toxicity Assessment of Fine Particulate Matters Emitted from the Combustion of Petrol and Diesel Fuels［J］. Science of the Total Environment， 2017， 605： 172-179.
[30] GB 17691-2018，重型柴油车污染物排放限值及测量方法（中国第六阶段）［S］.
[31] Zhang R， Zhang Y， Kook S. Morphological Variations of In-Flame and Exhaust Soot Particles Associated with Jet-to-Jet Variations and Jet-Jet Interactions in a Light-Duty Diesel Engine［J］. Combustion and Flame， 2017， 176： 377-390.
[32] CIMAC Working Group. Background Information on Black Carbon Emissions from Large Marine and Stationary Diesel Engines-Definition， Method Measurement， Emission Factors and Abatement Technologies［R］. Frankfurt： The International Council on Combustion Engines， 2012.
[33] Lack D A， Corbett J J. Black Carbon from Ships： A Review of the Effects of Ship Speed， Fuel Quality and Exhaust Gas Scrubbing［J］. Atmospheric Chemistry & Physics， 2012， 12（9）： 3985-4000.
[34] Corbett J J， Lack D A. Investigation of Appropriate Control Measures to Reduce Black Carbon Emissions from International Shipping［R］. London： International Maritime Organization， 2012.
[35] Ristimaki J， Hellen G， Lappi M. Chemical and Physical Characterization of Exhaust Particulate Matter from a Marine Medium Speed Diesel Engine［C］. Bergen： CIMAC Congress， 2010.
[36] Corporation W?rtsil?. Marine Market Emissions Reduced with New W?rtsil? 31SG Pure Gas Engine［EB/OL］. https： //www.wartsila.com/media/news/17-09-2019-marine-market-emissions-reduced-with-new-wartsila-31sg -pure-gas-engine-2528265， 2020-09-11.
[37] Zhang Z H， Balasubramanian R. Physicochemical and Toxicological Characteristics of Particulate Matter Emitted from a Non-Road Diesel Engine： Comparative Evaluation of Biodiesel-Diesel and Butanol-Diesel Blends［J］. Journal of Hazardous Materials， 2014， 264： 395-402.
[38] Pickett L M， Siebers D L. Soot in Diesel Fuel Jets： Effects of Ambient Temperature， Ambient Density， and Injection Pressure［J］. Combustion and Flame， 2004， 138（1-2）： 114-135.
[39] Han Z， Uludogan A， Hampson G J， et al. Mechanism of Soot and NO_x Emission Reduction Using Multiple-Injection in a Diesel Engine［R］. SAE TP-960633， 1996.
[40] Wu G， Zhou X， Li T. Temporal Evolution of Split-Injected Fuel Spray at Elevated Chamber Pressures［J］. Energies， 2019， 12： 4284-4296.
[41] Li T， Ogawa H. Analysis of the Trade-Off Between Soot and Nitrogen Oxides in Diesel-Like Combustion by Chemical Kinetic Calculation［J］. SAE International Journal of Engines， 2012， 5（2）： 94-101.
[42] Ogawa H， Li T， Miyamoto N. Characteristics of Low Temperature and Low Oxygen Diesel Combustion with Ultra-High EGR［J］. International Journal of Engine Research， 2007， 8 （4）： 365-378.
[43] Li T， Suzuki M， Shudo T， Ogawa H. Characteristics of Nano-Particulate Matter from Ultra-High EGR Low Temperature Diesel Combustion［J］. Transactions of the JSME （Series B）， 2008， 74（741）： 207-212.
[44] Li T， Suzuki M， Ogawa H. The Effect of Two-Stage Injection on Unburned Hydrocarbon and Carbon Monoxide Emissions in Smokeless Low Temperature Diesel Combustion with Ultra-High Exhaust Gas Recirculation［J］ International Journal of Engine Research， 2010， 11 （5）： 345-354.
[45] Li T， Moriwaki R， Ogawa H， et al. Dependence of Premixed Low-Temperature Diesel Combustion on Fuel Ignitability and Volatility［J］. International Journal of Engine Research， 2012， 13 （1）： 14-27.
[46] Schmid H， Weisser G. Marine Technologies for Reduced Emissions［C］. Amsterdam： Conference on Green Ship Technology， 2005.

船舶柴油机黑炭排放研究现状与展望

Research Prospect and Advancement of Black Carbon Emissions from Marine Diesel Engines

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