推进技术 ›› 1997, Vol. 18 ›› Issue (4): 69-74.

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二元稀土组合物对双基推进剂燃烧催化作用研究

单文刚,赵凤起,李上文   

  1. 西安近代化学研究所!西安;710065;西安近代化学研究所!西安;710065;西安近代化学研究所!西安;710065
  • 发布日期:2021-08-15

EFFECTS OF BINARY MIXTURES WITH RARE EARTH COMPOUNDS ON COMBUSTION OF DB PROPELLANTS

  1. Xi’an Modern Chemistry Research Inst., Xi’an, 710065;Xi’an Modern Chemistry Research Inst., Xi’an, 710065;Xi’an Modern Chemistry Research Inst., Xi’an, 710065
  • Published:2021-08-15

摘要: 研究了镧(铈)/铜盐、镧/铅盐、镧/铈组合物及镧/铈焙烧复合物对双基推进剂燃烧的催化作用,发现铜盐对稀土化合物的平台催化作用的改善有利,铅盐使稀土化合物的平台催化范围向高压区移动。镧/铈组(复)合物的燃烧催化作用与镧/铈比例密切相关,且使双基推进剂产生2个以上的平台燃烧区。稀土/铜盐对双基推进剂红外透过率的贡献高于其它二元稀土组合物。

关键词: 双基推进剂;平台推进剂;稀土化合物;燃烧催化剂

Abstract: The effects of binary mixtures composed of lanthanum (cerium) /copper salts,lanthanum/lead salts, lanthanum/cerium and binary composition of lanthanum/cerium prepared by baking on the combustion of DB propellants are studied. The resluts show that lanthanum/copper salts are advantageous to improve the plateau combustion of DB propellants, and lanthanum/lead salts remove the plateau combustion to the high pressure range. The combustion catalysis of lanthanum/cerium binary mixture (or composition) on DB propellants is related to the ratio of lanthanum/cerium and the binary mixtures (or composition) of La/Ce enable DB propellants to bring about more than two plateau combustion area.

Key words: Double base propellants;Mesa-burning propellant;Rare earth compound;Combustion catalyst