硝酸酯增塑聚醚推进剂中PB类助剂的作用机理

推进技术 ›› 2002, Vol. 23 ›› Issue (2): 164-167.

硝酸酯增塑聚醚推进剂中PB类助剂的作用机理

李洪旭,唐汉祥,邓剑如,周明川

湖北红星化学研究所湖北襄樊441003;湖北红星化学研究所湖北襄樊441003;湖北红星化学研究所湖北襄樊441003;湖北红星化学研究所湖北襄樊441003

发布日期:2021-08-15

Mechanism of PB aids added in nitrate plasticized propellants

Hubei Red Star Chemical Inst.,Xiangfan 441003,China;Hubei Red Star Chemical Inst.,Xiangfan 441003,China;Hubei Red Star Chemical Inst.,Xiangfan 441003,China;Hubei Red Star Chemical Inst.,Xiangfan 441003,China

Published:2021-08-15

摘要/Abstract

摘要： 为了解PB类功能助剂的作用机理 ,进行了接触角测试 ,XPS ,SEM和DMA试验。结果认为 :通过降低功能助剂自身极性 ,使之与HMX的表面性能相匹配 ,改善了HMX在粘合剂中的润湿性 ,从而改善药浆工艺性能 ;同时 ,保持对HMX有强的亲合力 ,吸附在HMX表面形成界面层 ,使推进剂保持良好的力学性能。最后提出了PB类助剂的作用机理。

关键词: 聚醚推进剂;助剂;工艺性能;力学性能

Abstract: In order to know mechanism of the PB auxiliary aids in polyether propellant,experiments of contract angle、XPS、SEM and DMA were conducted.Results show that the PB aid is fits to the surface properties of HMX and changes moisture HMX in binder by itself weaker polar of PB aid,so it can improve the processingability.PB agent keeps strong adherence to HMX and is absorbed in the surface of the HMX.The interface layer made by absorbing of PB aids can keep well mechanical properties of the propellant.At last,the mechanism of PB aids is founded.

Key words: Polyether propellant;Auxiliary agent;Processing property;Mechanical property

李洪旭,唐汉祥,邓剑如,周明川. 硝酸酯增塑聚醚推进剂中PB类助剂的作用机理[J]. 推进技术, 2002, 23(2): 164-167.