推进技术 ›› 2008, Vol. 29 ›› Issue (2): 253-256.

• • 上一篇    

增塑剂及燃烧催化剂对BAMO-THF复合推进剂性能的影响

翟进贤,杨荣杰,李建民   

  1. 北京理工大学材料科学与工程学院 北京100081;北京理工大学材料科学与工程学院 北京100082;北京理工大学材料科学与工程学院 北京100083
  • 发布日期:2021-08-15

Influences of plasticizers and combustion catalyst on performance of composite BAMO-THF propellants

  1. Coll.of Material Science and Engineering,Beijing Inst.of Technology,Beijing 100081,China;Coll.of Material Science and Engineering,Beijing Inst.of Technology,Beijing 100082,China;Coll.of Material Science and Engineering,Beijing Inst.of Technology,Beijing 100083,China
  • Published:2021-08-15

摘要: 采用混合硝酸酯(NG+DEGDN)和2,2-二硝基丙醇缩甲醛与2,2-二硝基丙醇缩乙醛混合物(A3)研究了增塑剂对3,3-二叠氮甲基氧丁环-四氮呋喃共聚醚(BAMO-THF)复合推进剂燃速、力学性能的影响。结果表明NG+DEGDN增塑的推进剂燃速和力学性能均优于A3。另外,研究了一种有机过渡金属燃速催化剂(代号OME)对BAMO-THF复合推进剂性能的影响。在显著提高BAMO-THF复合推进剂燃速同时,OME还可提高该体系力学性能。X射线光电子能谱(XPS)分析表明OME与粘结剂中叠氮基团存在作用力。

关键词: 复合推进剂;增塑剂;燃烧催化剂;燃速;力学性能

Abstract: The influences of the glyceryl trinitrate / diethyleneglycol dinitrate(NG+DEGDN) and bis(2,2-dinitropropyl)acetal / bis(2,2-dinitropropyl)formal(A3) plasticizers on performances of composite 3,3-bis(azidomethyl)oxetane-tetrahydrofuran co-polyether(BAMO-THF) propellants have been studied respectively.BAMO-THF/NG+DEGDN propellants showed higher burning rates and better mechanical properties than BAMO-THF/A3 propellants.In addition,the influence of a kind of organic transition metal combustion catalyst(OME) on burning rates and mechanical properties of BAMO-THF propellants has also been investigated.It was found that OME could increase the burning rates of BAMO-THF propellants and improve mechanical properties for BAMO-THF propellants.XPS(X-ray photoelectron spectra) analysis indicated that there existed interaction between OME and azide groups in BAMO-THF copolyether.

Key words: Composite propellants;Plasticizer;Combustion catalyst;Burning rate;Mechanical performance