关键词: 储氢合金;推进剂;催化作用;凝聚相反应;气相反应;爆热;燃速

Abstract: Al/AP/HTPB propellant and hydrogen storage alloy/AP/HTPB propellant were prepared and their properties were characterized by DSC,PDSC,explosion heat and burning rate test. DSC and PDSC test results show that hydrogen storage alloy has catalysis on condensed phase reactions of AP/HTPB propellant in which main decomposition temperature is decreased by 21.67 ℃ and 15.67 ℃ at 0.1MPa and 5MPa, respectively while condensed phase reaction heat is increased by 105.97% and 21.87% separately. Explosion heat test results show that hydrogen storage alloy has catalysis on gas phase reactions of AP/HTPB propellant in which gas phase reaction heat is increased by 4.74%. Burning rate test results show that hydrogen storage alloy can increase burning rate of AP/HTPB propellant. Further studies indicate that possible correlation exist between burning rate and explosion heat of Al/AP/HTPB propellant and hydrogen storage alloy/AP/HTPB propellant. The burning rate-explosion heat formula is summed up. 

Key words: Hydrogen storage alloy; Propellant; Catalysis; Condensed phase reaction; Gas phase reaction; Explosion heat; Burning rate