推进技术 ›› 2014, Vol. 35 ›› Issue (6): 846-851.

• 推进剂 燃料 • 上一篇    下一篇

聚三唑交联固体复合推进剂力学及燃烧性能研究

曲正阳,翟进贤,杨荣杰   

  1. 北京理工大学 材料学院,北京 100081;北京理工大学 材料学院,北京 100081;北京理工大学 材料学院,北京 100081
  • 发布日期:2021-08-15
  • 作者简介:曲正阳(1984—),男,博士生,研究领域为含能复合材料。E-mail:qhl_42798@sina.com

Study on the Mechanical and Burning Properties of Polytriazole Crosslinked Solid Composite Propellants

  1. School of Materials,Beijing Institute of Technology,Beijing 100081,China;School of Materials,Beijing Institute of Technology,Beijing 100081,China;School of Materials,Beijing Institute of Technology,Beijing 100081,China
  • Published:2021-08-15

摘要: 为了解决传统固体复合推进剂端羟基-异氰酸酯固化体系对水敏感以及与ADN,B粉等新组分不相容的问题,使用端炔基化的环氧乙烷-四氢呋喃共聚醚(PTPET)-多叠氮化合物组成新的固化体系,制备了常规配方S1、含键合剂配方S2、含ADN配方S3和含B粉配方S4的复合推进剂,对其力学性能和燃烧性能进行了测试。结果表明,室温下S1~S4的拉伸强度和断裂伸长率分别为0.60MPa,15%;0.63MPa,31%;0.40MPa,24%;0.72MPa,124%。在低温 (-40 ℃)下,S1~S4的拉伸强度和断裂伸长率分别为1.69MPa,>150%;2.10MPa,>149%;1.18MPa,>145%;2.10MPa,>149%。在高温 (60 ℃)下,S1~S4的拉伸强度和断裂伸长率分别为0.47MPa,23%;0.49MPa,21%;0.32MPa,17%;0.57MPa,84%。S2~S4在4~8 MPa下的燃速压力指数分别为0.49,0.52,0.38。4MPa压力,Ar气气氛下,S1~S4的爆热分别为6669,6695,6350,7014kJ/kg。总结了燃速和爆热的关系方程式。

关键词: 固体复合推进剂;端炔基环氧乙烷-四氢呋喃共聚醚;点击化学

Abstract: The traditional solid composite propellants with the terminal hydroxyl adhesive/isocyanate curing agent system are high water-sensitive,poorly compatible and stable with some novel solid additives such as ammonium dinitramide(ADN)and boron powders. These problems are expected to be solved by preparing the polytriazole cross-linked solid composite propellants using propargyl-terminated ethylene oxide-tetrahydrofuran copolymer(PTPET)as a adhesive and polyazide compound as an curing agent. The propellant samples were prepared containing different components: S1(common formula),S2(containing LBA-604),S3(containing ADN),S4(containing boron). The mechanical and burning properties of these samples were tested. The tensile stress and the broken strain are 0.60 MPa and 15%,0.63 MPa and 31%,0.40 MPa and 24%,0.72 MPa and 124% at room temperature; 1.69 MPa and above 150%,2.10 MPa and above 149%,1.18 MPa and above 145%,2.10 MPa and above 149% at -40 °C;0.47 MPa and 23%,0.49 MPa and 21%,0.32 MPa and 17%,0.57 MPa and 84% at 60 °C. The burning rate pressure exponents are 0.49,0.52 and 0.38 for S2~S4 at 4~8 MPa. Under argon atmosphere,the explosion heat is 6669,6695,6350 and 7014kJ/kg for S1~S4 at pressure of 4 MPa. The burning rate - explosion heat formula is summed up.

Key words: Solid composite propellants;Propargyl-terminated ethylene oxide - tetrahydrofuran copolymer;Click chemistry