C/C复合材料在再入模拟环境中烧蚀性能研究

推进技术 ›› 2014, Vol. 35 ›› Issue (8): 1080-1085.

C/C复合材料在再入模拟环境中烧蚀性能研究

王德文,査柏林,杨月诚,李红霞

第二炮兵工程大学动力工程系,陕西西安 710025;第二炮兵工程大学动力工程系,陕西西安 710025;第二炮兵工程大学动力工程系,陕西西安 710025;第二炮兵工程大学动力工程系,陕西西安 710025

发布日期:2021-08-15
作者简介:王德文(1976—),男,博士,研究领域为C/C复合材料烧蚀性能。
基金资助:
陕西省基金项目(2013JM6003)。

Ablation Characteristics of C/C Composites In Reentry Simulation Conditions

Department of Power Engineering,The Second Artillery Engineering University,Xi’an 710025,China;Department of Power Engineering,The Second Artillery Engineering University,Xi’an 710025,China;Department of Power Engineering,The Second Artillery Engineering University,Xi’an 710025,China;Department of Power Engineering,The Second Artillery Engineering University,Xi’an 710025,China

Published:2021-08-15

摘要/Abstract

摘要： 为了研究轴棒法编织的高密度碳/碳(C/C)复合材料在再入飞行时的烧蚀性能,采用热等离子体地面模拟再入烧蚀系统对C/C复合材料进行烧蚀试验。试验中分别采用氮气(N2)、氧气(O₂)和空气作为工作气体,对比研究C/C复合材料在不同环境中的烧蚀率和烧蚀性能。结果表明,三种情况下试样的烧蚀率和微观形貌有很大差异；纯氧气时氧化反应的线烧蚀率和质量烧蚀率分别为0.0423mm/s和0.0451g/s,大于纯氮气时氮化反应的0.0314mm/s和0.0338g/s,也大于空气成分时复合反应的0.0215mm/s和0.0208g/s；在试样烧蚀的热影响区发生轻微开裂；三种工况下的烧蚀机理不同,分别是碳的升华、碳的氧化和碳氮反应的某种组合。

关键词: 轴棒法C/C复合材料；再入；热等离子体；烧蚀率；微观形貌

Abstract: In order to study the ablation characteristics of axial carbon rod C/C composites,the ablation experiments were conducted by reentry simulation condition ablation system based on thermal plasma. The nitrogen(N2),oxygen(O₂)and air were taken as the operation gases,and the ablation characteristics and ablation rates of the specimens in different conditions were compared. The results show that the micro-morphologies and the ablation rates are different in three operation gases conditions. The linear and mass ablation rates are listed as follows: oxidation of O₂(0.0423mm/s and 0.0451g/s)> nitridation of N2(0.0314mm/s and 0.0338g/s)> composite reactions of air (0.0215mm/s and 0.0208g/s). There are some tiny cracks in thermal influencing areas,and the ablation mechanisms of the C/C composites in three operation gases conditions are differents. They are some combinations of sublimation of carbon,carbon oxide and carbon nitrogen reaction.

Key words: Axial carbon rod C/C composite material；Reentry；Thermal plasma；Ablation rate；Micromorphology

王德文,査柏林,杨月诚,李红霞. C/C复合材料在再入模拟环境中烧蚀性能研究[J]. 推进技术, 2014, 35(8): 1080-1085.

WANG De-wen,ZHA Bai-lin,YANG Yue-cheng,LI Hong-xia. Ablation Characteristics of C/C Composites In Reentry Simulation Conditions[J]. Journal of Propulsion Technology, 2014, 35(8): 1080-1085.

参考文献

[1] 车剑飞,黄洁雯,杨娟.复合材料及其工程应用[M].北京:机械工业出版社,2006.
[2] Hald H,Ullmann T.Reentry Flight and Ground Testing Experience with Hot Structures of C/C Material[R].AIAA 2003-1667.
[3] 苏勇,陈德江.电弧加热器变参数运行技术研究[J].实验流体力学,2005,19(3): 40-46.
[4] Ortelt,M,Weihs H,Fischer I,et al.Thermo-Mechanical Qualification Tests of Complex CMC Re-Entry Structures[J].Ceramic Engineering and Science Proceedings,2003,24(4): 281-287.
[5] Auweter-Kurtz M,Hilfer G,Habiger H,et al.Inverstigation of Oxidation Protected C/C Heat Shield Material in Different Plasma Wind Tunnels[J].Acta Astronaut,1999,45(2): 93-108.
[6] 王德文,杨月诚.地面模拟再入烧蚀系统研究[J].测试技术学报,2013,27(3).
[7] 沈志刚,赵小虎,王鑫.原子氧效应及其地面模拟试验[M].北京,国防工业出版社,2012.
[8] 张志成,潘梅林,刘初平,等.高超声速气动热和热防护[M].北京,国防工业出版社,2003.
[9] 范群波,王鲁,王福耻.等离子喷涂过程中喷枪出口处基本参量的预测方法[J].北京理工大学学报,2007,27(6): 546-550.
[10] 许承海,孟松鹤.多向编织炭/炭复合材料烧蚀/侵蚀特性研究[J].固体火箭技术,2011,34(6).
[11] 王磊,何国强.C/C组合喉衬烧蚀试验方法及微观形貌对比[J].固体火箭技术,2012,35(2).
[12] 张晓光,王长辉,刘宇,等.固体火箭发动机碳基材料喷管热化学烧蚀特性[J].推进技术,2012,33(1):93-97.(ZHANG Xiao-guang,WANG Chang-hui,LIU Yu.Carbon-Based Nozzle Thermochemical Erosion Characteristics in Solid Rocket Moters[J].Journal of Propulsion Technology,2012,33(1): 93-97.)
[13] 张晓光,王长辉,刘宇,等.小推力长时间工作固体火箭发动机C/C喉衬的烧蚀与沉积[J].推进技术,2011,32(4):586-590.(ZHANG Xiao-guang,WANG Chang-hui,LIU Yu.Erosion and Deposition of Carbon-Carbon nozzle Inserts in Low-Thrust Long-Duration Solid Rocket Moters[J].Journal of Propulsion Technology,2011,32(4): 586-590.)
[14] 王玲玲,嵇阿琳.三维针刺C/C-SiC复合材料的烧蚀性能[J].固体火箭技术,2012,35(4).
[15] 郭悦,孟松鹤,白光辉,等.烧蚀过程找你个发射光谱检测方法及装置[J].压电与声光,2008,30(4).
[16] 黄启忠.高性能炭/炭复合材料的制备、结构与应用[M].长沙: 中南大学出版社,2012.
[17] Duffa G,Vignoles J,Aspa Y.Ablation of C/C Composites:Investigation of Roughness Set-Up from Heterogeneous Reactions[J].Heat Mass Transfer,2005,48(16):3387-3401.(编辑:梅瑛)收稿日期:2013-08-11；修订日期:2013-10-12。基金项目:陕西省基金项目(2013JM6003)。作者简介:王德文(1976—),男,博士,研究领域为C/C复合材料烧蚀性能。E-mail:wangdewen@163.com