利用1.4μm附近的激光吸收光谱测量气体压强和H2O组分浓度

推进技术 ›› 2015, Vol. 36 ›› Issue (11): 1721-1727.

利用1.4μm附近的激光吸收光谱测量气体压强和H2O组分浓度

屈东胜,洪延姬,王广宇,王明东,潘虎

装备学院激光推进及其应用国家重点实验室，北京 101416,装备学院激光推进及其应用国家重点实验室，北京 101416,装备学院激光推进及其应用国家重点实验室，北京 101416,装备学院激光推进及其应用国家重点实验室，北京 101416,装备学院激光推进及其应用国家重点实验室，北京 101416

发布日期:2021-08-15
作者简介:屈东胜(1989—)，男，博士生，研究领域为瞬态流场诊断。
基金资助:
国家自然科学基金青年基金(21403299)。

Laser Absorption Spectroscopy near 1.4μm for Measurement of Gas Pressure and H2O Concentration

State Key Laboratory of Laser Propulsion and Application，Academy of Equipment，Beijing 101416，China,State Key Laboratory of Laser Propulsion and Application，Academy of Equipment，Beijing 101416，China,State Key Laboratory of Laser Propulsion and Application，Academy of Equipment，Beijing 101416，China,State Key Laboratory of Laser Propulsion and Application，Academy of Equipment，Beijing 101416，China and State Key Laboratory of Laser Propulsion and Application，Academy of Equipment，Beijing 101416，China

Published:2021-08-15

摘要/Abstract

摘要： 为了完善基于波长调制光谱的应用研究，利用1.4μm附近的H2O吸收谱线(7454.45cm-1)，研究了一种基于波长调制光谱测量气体压强和组分浓度的方法。基于谱线7454.45cm-1的4fpeak/2fpeak和2f/1f信号，详细分析了波长调制光谱方法测量的详细过程。结合仿真和实验，通过迭代算法在样品池内实现了气体压强和组分浓度的同时测量。实验结果表明:在500 ~ 1000K的温度范围内，压强和组分浓度的测量值与预测值基本符合，与预测值的最大误差分别在5%和4%以内。

关键词: 波长调制光谱；迭代算法；压强测量；组分浓度测量

Abstract: In order to improve the application of wavelength modulation spectroscopy，a method of measuring gas pressure and concentration using the H2O absorption transitions (7454.45cm-1) near 1.4μm is studied. The measurement of wavelength modulation spectroscopy based on the 4fpeak/2fpeak and 2f/1f signals of 7454.45cm-1 is analysed in detail. Combining simulation and experiment，the gas pressure and concentration are measured simultaneously in the static cell according to the iterative algorithm. Experimental results show that the measured gas pressure and concentration are consistent with the predicted values from 500K to 1000K. Compared with predicted values，the most relative errors are 5% and 4%，repestivery.

Key words: Wavelength modulation spectroscopy；Iterative algorithm；Pressure measurement；Concentration measurement

屈东胜,洪延姬,王广宇,王明东,潘虎. 利用1.4μm附近的激光吸收光谱测量气体压强和H2O组分浓度[J]. 推进技术, 2015, 36(11): 1721-1727.

QU Dong-sheng,HONG Yan-ji,WANG Guang-yu,WANG Ming-dong,PAN Hu. Laser Absorption Spectroscopy near 1.4μm for Measurement of Gas Pressure and H2O Concentration[J]. Journal of Propulsion Technology, 2015, 36(11): 1721-1727.

参考文献

[1] Goldenstein C S, Almodóvar C A, Jeffries J B, et al.High-Bandwidth Scanned Wavelength Modulation Spectroscopy Sensors for Temperature and H2O in a Rotating Detonation Engine[J]. Measurement Science and Technology, 2014, 25.
[2] Haylett D R, Cook R D, Davidson D F, et al. OH and C2H4 Species Time-Histories During Hexadecane and Diesel Ignition Behind Reflected Shock Waves[J]. Proceeding of the Combustion Institute, 2011, 33: 167-173.
[3] Hanson R K. Applications of Quantitative Laser Sensors to Kinetics, Propulsion and Practical Energy System[J].Proceedings of the Combustion Institute, 2011, 33: 1-40.
[4] Chao X, Jeffries J B, Hanson R K. Real-Time, in Situ,Continuous Monitoring of CO in a Pulverized-Coal-Fired Power Plant with a 2.3mm Laser Absorption Sensor[J]. Applied Physics B, 2013, 110: 359-365.
[5] Liu J T, Rieker G B, Jeffries J B, et al. Near-Infrared Diode Laser Absorption Diagnostic for Temperature and Water Vapor in a Scramjet Combustor[J]. Applied Optics, 2005, 44(31): 6701-6711.
[6] Houle A J, Nakakita K, Heltsley W N, et al. Diode Laser Absorption Measurements of Supersonic Flow in an Expansion Tube[C]. USA: 42nd AIAA/ASME/SAE/ASEE Joint Propulsion Conference & Exhibit, 2006, 1-7.
[7] Rieker G B, Jeffries J B, Hanson R K, et al. Diode Laser-Based Detection of Combustor Instabilities with Application to a Scramjet Engine[J]. Proceedings of the Combustion Institute, 2009, 32: 831-838.
[8] Cai T D, Jia H, Wang G S, et al. A Sensor for Measurements of Temperature and Water Concentration Using a Single Tunable Diode Laser near 1.4μm[J]. Sensors and Actuators A, 2009, 152: 5-12.
[9] Liu J T, Jeffries J B, Hanson R K, et al. Wavelength Modulation Absorption Spectroscopy with 2f Detection Using Multiplexed Diode Lasers for Rapid Temperature Measurements in Gaseous Flows[J]. Applied Physics B,2004, 78: 503-511.
[10] Rieker G B, Li H J, Liu X, et al. A Diode Laser Sensor for Rapid, Sensitive Measurements of Gas Temperature and Water Vapour Concentration at High Temperatures and Pressures[J]. Measurement Science and Technology, 2007, 18: 1195-1204.
[11] Henningsen J, Simonsen H. Quantitative Wavelength-Modulation Spectroscopy without Certified Gas Mixtures[J]. Applied Physics B, 2000, 70: 627-633.
[12] Mcgettrick A J, Duffin K, Johnstone W, et al. Tunable Diode Laser Spectroscopy with Wavelength Modulation: a Phasor Decomposition Method for Calibration-Free Measurements of Gas Concentration and Pressure[J].Journal of Lightwave Technology, 2008, 26(4): 432-440.
[13] Duffin K, Mcgettrick A J, Johnstone W, et al. Tunable Diode Spectroscopy with Wavelength Modulation: a Calibration-Free Approach to Recovery of Absolute Gas Absorption Line-Shapes[J]. Journal of Lightwave Technology, 2007, 25(10): 3114-3125.
[14] Li H J, Rieker G B, Liu X, et al. Extension of Wavelength-Modulation Spectroscopy to Large Modulation Depth for Diode Laser Absorption Measurements in High-Pressure Gases[J]. Applied Optics,2006,45:1052-1060.
[15] Rieker G B, Jeffries J B, Hanson R K, et al. Calibration-Free Wavelength-Modulation Spectroscopy for Measurements of Gas Temperature and Concentration in Harsh Environments[J]. Applied Optics,2009,48(29):5546-5560.
[16] Gamache B R, Kennedy S, Hawkins R, et al. Total Internal Partition Sums for Molecules in the Terrestrial Atmosphere[J]. Journal of Molecular Structure,2000,517: 407-425.
[17] Rothman L S, Gordon I E, Babikov Y, et al. The HITRAN 2012 Molecular Spectroscopic Database[J]. Journal of Quantitative Spectroscopy & Radiative Transfer, 2013, 130: 4-50.
[18] Liu X, Jeffries J B, Hanson R K, et al. Development of a Tunable Diode Laser Sensor for Measurements of Gas Turbine Exhaust Temperature[J]. Applied Physics B,2006, 82: 469-478.
[19] Liu X, Zhou X, Jeffries J B, et al. Experimental Study of H2O Spectroscopic Parameters in the near-IR[R]. AIAA 2005-0286.
[20] Sun K, Chao X, Sur R, et al. Wavelength Modulation Diode Laser Absorption Spectroscopy for High-Pressure Gas Sensing[J]. Applied Physics B, 2013, 110: 497-508.(编辑:张荣莉)　　　　　　　　　　　　　*　收稿日期:2015-05-19；修订日期:2015-07-25。基金项目:国家自然科学基金青年基金(21403299)。作者简介:屈东胜(1989—),男,博士生,研究领域为瞬态流场诊断。E-mail: hnqudongsheng@126.com