含有纳米铝颗粒的高密度悬浮燃料研究

推进技术 ›› 2016, Vol. 37 ›› Issue (5): 974-978.

含有纳米铝颗粒的高密度悬浮燃料研究

鄂秀天凤,彭浩,邹吉军,张香文,王莅

天津大学化工学院，先进燃料与化学推进剂教育部重点实验室，天津化学化工协同创新中心，天津 300072,天津大学化工学院，先进燃料与化学推进剂教育部重点实验室，天津化学化工协同创新中心，天津 300072,天津大学化工学院，先进燃料与化学推进剂教育部重点实验室，天津化学化工协同创新中心，天津 300072,天津大学化工学院，先进燃料与化学推进剂教育部重点实验室，天津化学化工协同创新中心，天津 300072,天津大学化工学院，先进燃料与化学推进剂教育部重点实验室，天津化学化工协同创新中心，天津 300072

发布日期:2021-08-15
作者简介:鄂秀天凤，女，硕士生，研究领域为航天燃料添加剂。E-mail: 512912355@qq.com 通讯作者:张香文，男，博士，教授，研究领域为航天燃料化学与技术。
基金资助:
装备预研项目(625010304)。

Study on Al NPs-Containing Suspension as High-Density Liquid Fuel

Key Laboratory of Advanced Fuel and Chemical Propellant of Ministry of Education，School of Chemical Engineering and Technology，Tianjin University，Collaborative Innovative Center of Chemical Science and Engineering Tianjin，Tianjin 300072，China,Key Laboratory of Advanced Fuel and Chemical Propellant of Ministry of Education，School of Chemical Engineering and Technology，Tianjin University，Collaborative Innovative Center of Chemical Science and Engineering Tianjin，Tianjin 300072，China,Key Laboratory of Advanced Fuel and Chemical Propellant of Ministry of Education，School of Chemical Engineering and Technology，Tianjin University，Collaborative Innovative Center of Chemical Science and Engineering Tianjin，Tianjin 300072，China,Key Laboratory of Advanced Fuel and Chemical Propellant of Ministry of Education，School of Chemical Engineering and Technology，Tianjin University，Collaborative Innovative Center of Chemical Science and Engineering Tianjin，Tianjin 300072，China and Key Laboratory of Advanced Fuel and Chemical Propellant of Ministry of Education，School of Chemical Engineering and Technology，Tianjin University，Collaborative Innovative Center of Chemical Science and Engineering Tianjin，Tianjin 300072，China

Published:2021-08-15

摘要/Abstract

摘要： 铝颗粒是一种高密度高能量的燃料添加剂，研究了一条通过表面改性使纳米铝颗粒分散在液体碳氢燃料中，进而制备高密度悬浮燃料的路线。采用三正辛基氧膦对铝颗粒进行表面改性，表征了改性颗粒的结构和在燃料中的分散稳定性，测试了悬浮燃料的密度、能量和粘度。结果表明，表面改性能够阻止铝颗粒的团聚和沉降，使其较长时间内稳定分散在高密度燃料HD-03中；含有铝颗粒的悬浮燃料的密度和体积热值显著提高，保持液体状态和良好流动性。其中，含有10wt%和30wt%铝颗粒时的燃料密度分别为1.06g/mL，1.14g/mL，体积能量分别为44.3MJ/L，45.4MJ/L，动力粘度分别为80mPa·s，2000mPa·s。

关键词: 应用化学；高密度燃料；含能纳米颗粒；推进剂；悬浮燃料

Abstract: Aluminum particles have been used as an additive of high density and energy to improve the energy of fuel and propellant. Here the possibility of preparing suspension fuel was studied by modifying the surface of Al nanoparticles (NPs) and adding them into liquid fuel. Trioctylphosphine oxide (TOPO) was used as the surfactant to modify the NP surface，and the particle structure and dispersion stability，as well as the density，energy and viscosity of suspension fuel were analyzed. It is found that the surface modification could inhibit the agglomeration and settlement of NPs，and made them disperse stably in liquid hydrocarbon fuel like HD-03 for a relatively long time. The density and volumetric energy of the fuel increased significantly，and it could flow freely like common liquid fuel. With 10wt% and 30wt% NPs added，the density，volumetric energy and viscosity of the fuel were 1.06g/mL and 1.14g/mL，44.3MJ/L and 45.4MJ/L，80mPa·s and 2000mPa·s，respectively.

Key words: Applied chemistry；High-density fuel；Energetic nanoparticle；Propellant；Suspension fuel

鄂秀天凤,彭浩,邹吉军,张香文,王莅. 含有纳米铝颗粒的高密度悬浮燃料研究[J]. 推进技术, 2016, 37(5): 974-978.

E Xiu-tian-feng,PENG Hao,ZOU Ji-jun,ZHANG Xiang-wen,WANG Li. Study on Al NPs-Containing Suspension as High-Density Liquid Fuel[J]. Journal of Propulsion Technology, 2016, 37(5): 974-978.

参考文献

[1] Chung HS, Chen CSH, Kremer RA, et al. Recent Developments in High-Energy Density Liquid Hydrocarbon Fuels[J]. Energy & Fuels, 1999, 13(3): 641-649.
[2] Wilson GR, Edwards T, Corporan E, et al. Certification of Alternative Aviation Fuels and Blend Components[J]. Energy & Fuels, 2013, 27(2): 962-966.
[3] Hui X, Kumar K, Sung CJ, et al. Experimental Studies on the Combustion Characteristics of Alternative Jet Fuels[J]. Fuel, 2012, 98(1): 176-182.
[4] Sibi MG, Singh B, Kumar R, et al. Single-Step Catalytic Liquid-Phase Hydroconversion of DCPD into High Energy Density Fuel exo-THDCPD[J]. Green Chemistry, 2012, 14(2): 976-983.
[5] 邹吉军, 张香文, 王莅, 等. 高密度液体碳氢燃料合成及应用进展[J]. 含能材料, 2007, 15(4): 411-415.
[6] 邹吉军, 郭成, 张香文, 等. 航天推进用高密度液体碳氢燃料:合成与应用[J]. 推进技术, 2014, 35(10): 1419-1425. (ZOU Ji-jun, GUO Cheng, ZHANG Xiang-wen, et al. High-Density Liquid Hydrocarbon Fuels for Aerospace Propulsion: Synthesis and Application[J]. Journal of Propulsion Technology, 2014, 35(10): 1419-1425.)
[7] Huang MY, Wu JC, Shieu FS, et al. Isomerization of Endo-Tetrahydrodicyclopentadiene over Clay-Supported Chloroaluminate Ionic Liquid Catalysts[J]. Journal of Molecular Catalysis A-Chemical, 2010, 315(1): 69-75.
[8] Kim J, Han J, Kwon TS, et al. Oligomerization and Isomerization of Dicyclopentadiene over Mesoporous Materials Produced from Zeolite Beta[J]. Catalysis Today, 2014, 232(1): 69-74.
[9] Zou J-J, Xiong Z, Zhang X, et al. Kinetics of Tricyclopentadiene Hydrogenation over Pd-B/γ-Al2O3 Amorphous Catalyst[J]. Industrial & Engineering Chemistry Research, 2007, 46(13): 4415-4420.
[10] Li Y, Zou J-J, Zhang X, et al. Product Distribution of Tricyclopentadiene from Cycloaddition of Dicyclopentadiene and Cyclopentadiene: A Theoretical and Experimental Study[J]. Fuel, 2010, 89(9): 2522-2527.
[11] Wang L, Zhang X, Zou J-J, et al. Acid-Catalyzed Isomerization of Tetrahydrotricyclopentadiene: Synthesis of High-Energy-Density Liquid Fuel[J]. Energy & Fuels, 2009, 23(5): 2383-2388.
[12] Wang L, Zou J-J, Zhang X, et al. Rearrangement of Tetrahydrotricyclopentadiene Using Acidic Ionic Liquid: Synthesis of Diamondoid Fuel[J]. Energy & Fuels, 2011, 25(4): 1342-1347.
[13] 王磊, 张香文, 邹吉军, 等. 密度大于1的高密度液体碳氢燃料合成及复配研究[J]. 含能材料, 2009, 17(2): 157-160.
[14] 张远君. 金属推进燃料的研究进展[J]. 推进技术, 1981, 2(3): 66-74.
[15] Perez JPL, McMahon BW, Anderson SL. Functionalization and Passivation of Boron Nanoparticles with a Hypergolic Ionic Liquid[J]. Journal of Propulsion and Power, 2013, 29(2): 489-495.
[16] Yetter RA, Risha GA, Son SF. Metal Particle Combustion and Nanotechnology[J]. Proceedings of the Combustion Institute, 2009, 32(2): 1819-1838.
[17] E XTF, Zhi X, Zhang Y, et al. Jet Fuel Containing Ligand-Protecting Energetic Nanoparticles: A Case Study of Boron in JP-10[J]. Chemical Engineering Science, 2015, 129(16): 9-13.
[18] Cui Y, Zhao S, Tao Do, et al. Synthesis of Size-Controlled and Discrete Core-Shell Aluminum Nanoparticles with a Wet Chemical Process[J]. Materials Letters, 2014, 121(1): 54-57.
[19] Guo Y, Yang Y, Fang W, et al. Resorcinarene-Encapsulated Ni-B Nano-Amorphous Alloys Forquasi-Homogeneous Catalytic Cracking of JP-10[J]. Applied Catalysis A-General, 2014, 469(17): 213-220.
[20] XTF E, Zhang Y, Zou J-J, et al. Oleylamine-Protected Metal (Pt, Pd) Nanoparticles for Pseudohomogeneous Catalytic Cracking of JP-10 Jet Fuel[J]. Industrial & Engineering Chemistry Research, 2014, 53(31): 12312-12318.
[21] 王方, 鄂秀天凤, 邹吉军, 等. 油溶性钯纳米颗粒催化高密度燃料点火燃烧研究[J]. 推进技术, 2016, 37(1). (WANG Fang, E Xiu-tian-feng, ZOU Ji-jun, et al. Hydrocarbon Fuel-Soluble Palladium Nanoparticles for Catalytic Combustion of High Density Fuel[J]. Journal of Propulsion Technology, 2016, (1).)
[22] Mandilas C, Karagiannakis G, Konstandopoulos AG, et al. Study of Basic Oxidation and Combustion Characteristics of Aluminum Nanoparticles under Engine Like Conditions[J]. Energy & Fuels, 2014, 28(5): 3430-3441.　　　　　　　　　　　　　*　收稿日期:2015-01-15；修订日期:2015-03-20。基金项目:装备预研项目(625010304)。作者简介:鄂秀天凤,女,硕士生,研究领域为航天燃料添加剂。E-mail: 512912355@qq.com通讯作者:张香文,男,博士,教授,研究领域为航天燃料化学与技术。E-mail: zhangxiangwen@tju.edu.cn(编辑:张荣莉)