氢气添加对RP-3航空煤油着火特性的影响

推进技术 ›› 2016, Vol. 37 ›› Issue (9): 1742-1751.

氢气添加对RP-3航空煤油着火特性的影响

刘宇,曾文,马洪安,陈保东

沈阳航空航天大学航空航天工程学院，辽宁沈阳 110136,沈阳航空航天大学航空航天工程学院，辽宁沈阳 110136,沈阳航空航天大学航空航天工程学院，辽宁沈阳 110136,沈阳航空航天大学航空航天工程学院，辽宁沈阳 110136

发布日期:2021-08-15
作者简介:刘宇，男，讲师，博士，研究领域为航空发动机燃料燃烧实验与化学反应机理。 E-mail: liuyu_201409@163.com 通讯作者:曾文，教授，博士后，研究领域为航空发动机燃烧过程与排放物生成的数值研究。
基金资助:
国家自然科学基金(51376133)；辽宁省自然科学基金(2013024009)；

Effects of Hydrogen Addition on Ignition

School of Aerospace Engineering，Shenyang Aerospace University，Shenyang 110136，China,School of Aerospace Engineering，Shenyang Aerospace University，Shenyang 110136，China,School of Aerospace Engineering，Shenyang Aerospace University，Shenyang 110136，China and School of Aerospace Engineering，Shenyang Aerospace University，Shenyang 110136，China

Published:2021-08-15

摘要/Abstract

摘要： 为了揭示可燃小分子气体H2添加对RP-3航空煤油着火特性的影响，采用激波管实验装置对RP-3航空煤油的着火特性进行了实验测量，获得了多工况下RP-3航空煤油的着火延迟时间。以RP-3航空煤油的正癸烷、甲苯和丙基环己烷三组分模拟替代燃料的燃烧反应机理为基础，构建了RP-3/H2混合燃料的Zeng-Jachimowski燃烧反应机理，并对该机理进行了验证。采用该机理对RP-3/H2混合燃料多工况下的着火延迟时间进行计算与分析，结果表明:Zeng-Jachimowski机理可以较好预测高温条件下RP-3/H2混合气着火特性；当H2添加比小于70%时，着火延迟时间随H2添加缓慢减小，当H2添加比大于90%时，RP-3航空煤油/氢气混合气活性显著提升，着火延迟时间随H2添加急剧减小；通过对H，OH和O活性自由基的浓度及H自由基生成速率ROP分析解释了H2添加对RP-3航空煤油着火延迟时间的非线性影响。

关键词: 氢气；RP-3航空煤油；反应机理；着火延迟时间；活性自由基

Abstract: In order to reveal the effects of H2 addition on the ignition characteristics of RP-3 kerosene，the ignition characteristics of RP-3 was measured in a chemical shock tube and the ignition delay time of the kerosene at various conditions were obtained. Based on the detailed reaction mechanism of RP-3 kerosene’s surrogate fuel which includes n-decane，toluene and propyl cyclohexane，a Zeng-Jachimowski reaction mechanism for the RP-3/H2 mixed fuel was developed and validated. This reaction mechanism was adopted to calculate and analyze the ignition delay time of RP-3/H2 mixture at various conditions，and the results show that the Zeng-Jachimowski mechanism can well predict the ignition delay time of RP-3/H2 mixture under high temperature condition. For H2 addition less than 70%，the ignition delay time decreases with H2 addition slowly，and for the H2 addition more than 90%，the ignition delay time decreases with H2 addition dramatically. Analysis of H, O，OH active radical concentration and H ROP has interpreted the non-linear influence of H2 addition on the ignition delay time of RP-3 kerosene.

Key words: Hydrogen；RP-3 kerosene；Reaction mechanism；Ignition delay time；Active radical

刘宇,曾文,马洪安,陈保东. 氢气添加对RP-3航空煤油着火特性的影响[J]. 推进技术, 2016, 37(9): 1742-1751.

LIU Yu,ZENG Wen,MA Hong-an,CHEN Bao-dong. Effects of Hydrogen Addition on Ignition[J]. Journal of Propulsion Technology, 2016, 37(9): 1742-1751.

参考文献

[1] Marshall L, Bahm C, Corpening G, et al. Overview with Results and Lessons Learned of the X-43A Mach 10 Flight[R]. AIAA 2005-3336.
[2] 李宁, 李旭昌, 张涵, 等. 超声速燃烧火焰稳定技术及其发展综述[J]. 飞航导弹, 2014, 5: 60-67.
[3] 席文雄, 王振国, 刘卫东, 等. 双模态超燃冲压发动机点火方案对比试验[J]. 推进技术, 2013, 34(3): 383-389. (XI Wen-xiong, WANG Zhen-guo, LIU Wei-dong, et al. Experimental Comparison on the Scheme of Ignition in Dual-Mode Scramjet[J]. Journal of Propulsion Technology, 2013, 34(3): 383-389.)
[4] 韦宝禧, 欧东, 闫明磊, 等. 超燃燃烧室等离子体点火和火焰稳定性能[J]. 北京航空航天大学学报, 2012, 38(12): 1572-1576.
[5] 王苏, 崔季平, 范秉诚, 等. 促进剂对高碳数碳氢燃料点火特性的影响[J]. 实验流体力学, 2007, 21(2): 25-28.
[6] 龚景松, 杨庆涛, 候凌云, 等. 乙醇煤油混合燃料热解特性实验研究[J]. 工程热物理学报, 2009, 30(9): 1617-1619.
[7] Lifshitz A, Scheller K, Burcat A, et al. Shock-Tube Investigation of Ignition in Methane/Oxygen/Argon Mixtures[J]. Combustion and Flame, 1971, 16(3): 311-321.
[8] Ju Y, Niioka T. Ignition Simulation of Methane/Hydrogen Mixtures in a Supersonic Mixing Layer[J]. Combustion and Flame, 1995, 102(4): 462-470.
[9] Wang Jinhua, Huang Zuohua, Tang Chenglong, et al. Effect of Hydrogen Addition on Early Flame Growth of Lean Burn Natural Gas-Air Mixture[J]. International Journal of Hydrogen Energy, 2010, 35(13): 7246-7252.
[10] 夏萌, 林宇震, 张驰. 正十烷/氢气/空气点火延迟特性数值分析[J]. 中国矿业大学学报, 2014, 43(4): 721-725.
[11] Westbrook C K, Pitz W J, Herbinet O, et al. A Comprehensive Detailed Chemical Kinetic Reaction Mechanism for Combustion of n-Alkane Hydrocarbons from n-Octane to n-Hexadecane[J]. Combustion and Flame, 2009, 156(1): 181-199.
[12] Hui Xin , Zhang Chi , Xia Meng, et al. Effects of Hydrogen Addition on Combustion Characteristics of n-Necane/Air Mixtures[J]. Combustion and Flame, 2014, 161: 2252-2262.
[13] Frolov S M, Medvedev S N, Basevich V Ya, et al. Self-Ignition of Hydrocarbon-Hydrogen-Air Mixtures[J]. International Journal of Hydrogen Energy, 2013, 38(1): 4177-4184.
[14] 范学军, 俞刚. 大庆RP-3航空煤油热物性分析[J]. 推进技术, 2006, 27(2): 187-192. (FAN Xue-jun, YU Gang. Analysis of Thermophysical Properties of Daqing RP-3 Aviation Kerosene[J]. Journal of Propulsion Technology, 2006, 27(2): 187-192.)
[15] 曾文, 李海霞, 马洪安, 等. RP-3航空煤油模拟替代燃料的化学反应详细机理[J]. 航空动力学报, 2014, 29(12): 2810-2816.
[16] 曾文, 李海霞, 马洪安, 等. RP-3航空煤油模拟替代燃料的化学反应简化机理[J]. 推进技术, 2014, 35(8): 1139-1145. (ZENG Wen, LI Hai-xia, MA Hong-an, et al. Reduced Chemical Reaction Mechanism of Surrogate Fuel for RP-3 Kerosene[J]. Journal of Propulsion Technology, 2014, 35(8): 1139-1145.)
[17] Jachimowski C J. An Analytical Study of the Hydrogen-Air Reaction Mechanism with Application to Scramjet Combustion[R]. NASA TP-2791.
[18] Gersen S, Anikin N B, Mokhov A V, et al. Ignition Properties of Methane/Hydrogen Mixtures in a Rapid Compression Machine[J]. International Journal of Hydrogen Energy, 2008, 33(7): 1957-1964.
[19] Slack M, Grillo A. Investigation of Hydrogen-Air Ignition Sensitized by Nitric Oxide and by Nitrogen Dioxide[R]. NASA CR-2896. (编辑:史亚红)　　　　　　　　　　　　　*　收稿日期:2015-08-21；修订日期:2015-10-28。基金项目:国家自然科学基金(51376133)；辽宁省自然科学基金(2013024009)；辽宁省博士启动基金(20141076)；沈阳市科技攻关项目(F13024200)。作者简介:刘宇,男,讲师,博士,研究领域为航空发动机燃料燃烧实验与化学反应机理。 E-mail: liuyu_201409@163.com通讯作者:曾文,教授,博士后,研究领域为航空发动机燃烧过程与排放物生成的数值研究。E-mail: zengwen928@sohu.com