PEDOT/RDX复合粒子的制备与性能研究

推进技术 ›› 2017, Vol. 38 ›› Issue (11): 2628-2633.

• 先进材料　推进剂　燃料 • 上一篇下一篇

PEDOT/RDX复合粒子的制备与性能研究

时志权,王惠,陆德炜

上海航天化工应用研究所，浙江湖州 313000,上海航天化工应用研究所，浙江湖州 313000,上海航天化工应用研究所，浙江湖州 313000

发布日期:2021-08-15
作者简介:时志权，男，博士，高级工程师，研究领域为推进剂原材料合成、表面包覆及其应用。
基金资助:
上海市自然科学基金(14ZR1420500)。

Study on Preparation and Properties of PEDOT/RDX Composite Particles

Shanghai Aerospace Chemical Engineering Institute，Huzhou 313000，China,Shanghai Aerospace Chemical Engineering Institute，Huzhou 313000，China and Shanghai Aerospace Chemical Engineering Institute，Huzhou 313000，China

Published:2021-08-15

摘要/Abstract

摘要： 为改善含RDX复合固体推进剂的安全性能和力学性能，采用化学包覆方法，对RDX进行了聚3，4-乙烯二氧噻吩(PEDOT)包覆处理，并对包覆前后的RDX进行SEM，FTIR，DTA，TGA，XPS和XRD分析表征。对包覆RDX的表面导电性能进行测试，导电率达5×10-5S/cm，对包覆RDX的机械感度进行了测试，撞击、摩擦感度得到显著降低。进一步对PEDOT/RDX和RDX的PET四组元推进剂进行了装药，得出包覆后推进剂的拉伸性能比未包覆的有显著提高，同时PEDOT包覆RDX后，固体推进剂的能量没有损失。

关键词: RDX；聚3，4-乙烯二氧噻吩；感度；表面改性；复合固体推进剂

Abstract: To improve the safe and mechanical properties of composite solid propellant with RDX，chemical modification method was used to modify RDX with Poly (3，4-ethylenedioxythiophenes). The microstructure and morphology of modified RDX and RDX were characterized by SEM，FTIR，DTA，TGA，XPS and XRD measurements. The surface conductivity of modified RDX had greatly increased to 5×10-5 S/cm. The impact sensitivity and friction sensitivity of modified RDX had greatly decreased. In addition，PET propellants with PEDOT/RDX and RDX were manufactured，and the tensile property of PET propellant with PEDOT/RDX was higher than that with RDX，and the energy had no decrease.

Key words: RDX；Poly (3，4-ethylenedioxythiophenes)；Sensitivity；Surface modification；Composite solid propellant

时志权,王惠,陆德炜. PEDOT/RDX复合粒子的制备与性能研究[J]. 推进技术, 2017, 38(11): 2628-2633.

SHI Zhi-quan,WANG Hui,LU De-wei. Study on Preparation and Properties of PEDOT/RDX Composite Particles[J]. Journal of Propulsion Technology, 2017, 38(11): 2628-2633.

参考文献

[1] 刘波, 刘少武, 张远波, 等.RDX降感技术研究进展[J]. 化学推进剂与高分子材料, 2012, 10(1): 67-70.
[2] 安崇伟, 宋小兰, 王毅, 等. 硝胺类炸药颗粒表面包覆的研究进展[J]. 含能材料, 2007, 15(2): 188-192.
[3] Oberth A E, Bruenner R S. Binder Filler Interaction and Propellant Mechanical Properties[J]. Transaction of Society of Theology, 1965, 9(6): 165-171.
[4] Somoza. Process for Reducing Sensitivity in Explosives[P]. US: P5279492, 1994.
[5] Bowers R C, Romans J B, Zisman W A. Mechanisms Involved in Impact Sensitivity and Desensitization of RDX[J]. Industrial & Engineering Chemistry Product Research and Development, 1973, 12(1): 2-13.
[6] Singh Sanjev K, Samuels Philip, Capellos Christos, et al. Process for Crystalline Explosives Containing Halogenated Wax Binders[P]. US: P8216404, 2012-07-10.
[7] Manning T G, Strauss B. Reduction of Energetic Filler Sensitivity in Propellants through Coating[P]. US: P6524706, 2003.
[8] 李丹, 王晶禹, 姜夏冰, 等. 硬脂酸包覆超细RDX及其撞击感度[J]. 火炸药学报, 2009, 32(1): 40-43.
[9] 陆铭, 陈煜, 罗运军, 等. 水性聚氨酯乳液的制备及其包覆RDX的研究[J]. 推进技术, 2005, 26(1):89-92. (LU Ming, CHEN Yu, LUO Yun-jun, et al. Preparation of Waterborne Polyurethane Latex and Study on Its Cladding of RDX[J]. Journal of Propulsion Technology, 2005, 26(1): 89-92.)
[10] 李宁, 肖乐勤, 菅晓霞, 等. GAP基含能聚氨酯弹性体包覆RDX的研究[J]. 固体火箭技术, 2012, 35(2): 212-215.
[11] 吴文辉, 黎玉钦, 张聪, 等. 中性聚合物键合剂对硝胺推进剂中相界面的作用[J]. 推进技术, 2001, 22(4): 337-340. (WU Wen-hui, LI Yu-qin, ZHANG Cong, et al. Interfacial Reinforcement of Neutral Polymeric Bonding Agents (NPBA) in Nitramine Propellants[J]. Journal of Propulsion Technology, 2001, 22(4): 337-340.)
[12] Kim C S. Development of Neutral Polymeric Bonding Agent for Propellants with Polar Composites Filled with Organic Nitramine Crystals[J]. Propellants, Explosives, Pyrotechnics, 1992, 17(1): 38-42.
[13] 陆明, 周新利. RDX的TNT包覆钝感研究[J]. 火炸药学报, 2006, 29(6): 16-18.
[14] Corradi R, Armes S P. Chemical Synthesis of Poly(3, 4-Ethylenedioxy-Thiophene)[J]. Synthetic Metals, 1997, 84(1-3): 453-454.
[15] Fallis Stephen, Irvin Jennifer A. Electrostatic Charge Dissipation Compositions Including Energetic Particles[P]. US: P7931762, 2011-04-26.
[16] 李江存, 焦清介, 任慧, 等. 不同键合剂与RDX表界面作用[J]. 含能材料, 2009, 17(3): 274-277.
[17] Choi J W, Han M G, Kim S Y, et al. Poly (3, 4-Ethylenedioxythiophene) Nanoparticles Prepared in Aqueous DBSA Solutions[J]. Synthetic Metals, 2004, 141(3): 293-299.　　　　　　　　　　　　　*　收稿日期:2016-07-13；修订日期:2016-10-13。基金项目:上海市自然科学基金(14ZR1420500)。作者简介:时志权,男,博士,高级工程师,研究领域为推进剂原材料合成、表面包覆及其应用。E-mail: shizhi163@163.com(编辑:梅瑛)

PEDOT/RDX复合粒子的制备与性能研究

Study on Preparation and Properties of PEDOT/RDX Composite Particles

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