超临界压力下乳化煤油比定压热容测量 *

推进技术 ›› 2018, Vol. 39 ›› Issue (7): 1660-1666.

超临界压力下乳化煤油比定压热容测量 *

贺宇锋¹,郭亚军¹,冯松²,毕勤成²

西安建筑科技大学环境与市政工程学院，陕西西安 710055,西安建筑科技大学环境与市政工程学院，陕西西安 710055,西安交通大学动力工程多相流国家重点实验室，陕西西安 710049,西安交通大学动力工程多相流国家重点实验室，陕西西安 710049

发布日期:2021-08-15
作者简介:贺宇锋，男，硕士生，研究领域为超临界条件下吸热型碳氢燃料热物理性质。 E-mail: 924134163@qq.com 通讯作者:郭亚军，女，博士，副教授，研究领域为新型环保节能换热器研发、蒸汽发生器相变传热研究。
基金资助:
青年科学基金项目( 21306147)；国家博士后科学基金项目( 2013M532044)。

Measurementof Isobaric Specific Heatof Emulsified Keroseneat Supercritical Pressure

School of Environmental and Municipal Engineering，Xi’an University of Architecture & Technology， Xi’an 710055，China,School of Environmental and Municipal Engineering，Xi’an University of Architecture & Technology， Xi’an 710055，China,State Key Laboratory of Multiphase Flow in Power Engineering，Xi’an Jiaotong University，Xi’an 710049，China and State Key Laboratory of Multiphase Flow in Power Engineering，Xi’an Jiaotong University，Xi’an 710049，China

Published:2021-08-15

摘要/Abstract

摘要： 为了准确测量高温高压下乳化煤油的比定压热容，基于能量守恒的量热计理论，搭建了一套流动型比定压热容在线测量系统。系统温度测量范围为 301～900K，测量压力可达 10MPa。通过去离子水和质量比 1:1正辛烷-正庚烷混合物对测量系统进行标定，实验结果与文献值进行比较，最大相对误差小于 ±1%，相对误差绝对平均值在 0.46%以内。在此基础上，对含水质量分数为 10%，20%，30%， 50%的四种乳化煤油比定压热容进行测量，温度为 301～880K，压力为 3MPa。实验结果与航空煤油 RP-3进行对比，结果表明:相同工况下，乳化煤油比定压热容较大，吸热能力更强，冷却壁温效果更好。该系统的搭建为进一步研究乳化碳氢燃料比定压热容创造了条件。

关键词: 超临界压力；乳化煤油；定压比热容；在线测量

Abstract: A set of constant pressure heat capacity on-line measurement system based on the energy conser.vation calorimeter theory is established in order to accurately measure the specific heat capacity of emulsified ker.osene at high temperature and pressure，which temperature covering from 301 to 900K and pressures up t 10MPa. The deionized water and the binary mixtures of n-octane and n-heptane with a mass ratio of 1:1 were measured for the calibration of the measurement system. Compared with the literature values，the experimental re.sults show that the maximum relative deviations were below ±1% and the absolute average relative deviations were within 0.46%. The isobaric specific heat capacity of emulsified kerosene with water content fraction of 10%， 20%，30% and 50% were measured at the temperatures from 301 to 880K and the pressure of 3MPa. Compared with those of aviation kerosene RP-3，the experimental results show that the isobaric specific heat capacity of emulsified kerosene is larger and the heat capacity is stronger and the effect of cooling wall temperature is better.The construction of the system creates the conditions to further study isobaric specific heat capacity of the emulsi.fied hydrocarbon fuel.

Key words: Supercritical pressure；Emulsified fuel；Specific heat capacity；On-line measurement

贺宇锋,郭亚军,冯松,毕勤成. 超临界压力下乳化煤油比定压热容测量 *[J]. 推进技术, 2018, 39(7): 1660-1666.

HE Yu-Feng¹,GUO Ya-jun¹,FENG Song²,BI Qin-Cheng². Measurementof Isobaric Specific Heatof Emulsified Keroseneat Supercritical Pressure[J]. Journal of Propulsion Technology, 2018, 39(7): 1660-1666.

参考文献

[1] Edwards T.Liquid Fuels and Propellants for Aerospace Propulsion:1903-2003[J].Journal of Propulsion and Power,2003,19(6): 1089-1107.
[2] Fry S.A Century of Ramjet Propulsion Technology Evo.lution[J].Journal of Propulsion and Power,2004,20(1): 27-58.
[3] 仲峰泉,范学军,俞刚 .带主动冷却的超声速燃烧室传热分析[ J].推进技术, 2009,30(5): 513-517.(ZHONG Feng-quan,FAN Xue-jun,YU Gang.HeatTransfer Analysis for Actively Cooled Supersonic Com.bustor[J].Journal of Propulsion Technology,2009,30(5): 513-517.)
[4] Radovanovic M,Venderbosch R H,Prins W,et al.Some Remarks on the Viscosity Measurement of Pyroly.sis Liquids[J].Biomass and Bioenergy,2000,18(3): 209-222.
[5] Pecar D,Dolecek V.Isothermal Compressibilities and Isobaric Expansibilities of Pentane,Hexane,Heptane and Their Binary and Ternary Mixtures from Density Measurements[J].Fluid Phase Equilibria,2003,211(1): 109-127.
[6] Huang H,Spadaccini L J,Sobel D R.Fuel-Cooled Thermal Management for Advance Aeroengines[J].Journal of Engineering for Gas Turbines and Power-Transactions of the ASME,2004,126(2): 284-293.
[7] Gascoin N,Gillard P,Dufour E,et al.Validation of Transient Cooling Modeling for Hypersonic Application[J].Journal of Thermophysics and Heat Transfer, 2007,21(1): 86-94.
[8] Yue D T,Tan Z C,DiY Y,et al.Specific Heat Capaci.ty and Thermal Conductivity of Foam Glass(Type150P) at Temperatures from 80 to 400K[J].International Jour.nal of Thermophysics,2006,27(1): 270-281.
[9] Lexa D,Leibowitz L.Differential Thermal Analysis andDifferential Scanning Calorimetry Characterization of Materials[M].Manhattan: John Wiley & Sons,Inc., 2002.
[10] Johnson J F,Gill P S.Analytical Calorimetry[M].San Francisco: Springer US,1977.
[11] 黄淑君,郭亚军,杨竹强,等 .吸热型碳氢燃料的定压比热测量研究[ J].热能动力工程, 2015,30(6): 833-836.
[12] Deng Hongwu,Zhu Kun,Xu Guoqiang,et al.Isobaric Specific Heat Capacity Measurement for Kerosene RP-3in the Near-Critical and Supercritical Regions[J].Jour.nal of Chemical and Engineering Data,2012,57(2): 263-268.)
[13] 范学军,俞刚 .大庆 RP-3航空煤油热物性分析[J].推进技术, 2006,27(2): 187-192.(FAN Xue-jun,YU Gang.Analysis of Thermophysical Properties of Daqing RP-3 Aviation Kerosene[J].Journal of Pro.pulsion Technology,2006,27(2): 187-192.)
[14] 李勋锋,仲峰泉,范学军,等 .超临界压力下航空煤油圆管流动和传热的数值研究[ J].推进技术, 2010, 31(4): 467-472.(LI Xun-feng,ZHONG Feng-quan, FAN Xue -jun,et al.Numerical Study of ConvectiveHeat Transfer of Aviation Kerosene Flows in Pipe at Su.percritical Pressure[J].Journal of Propulsion Technolo.gy,2010,31(4): 467-472.)
[15] Edwards T,Zabamick S.Supercritical Fuel Deposition Mechanism[J].Industrial & Engineering Chemistry Re.search,1993,32(12): 3117-3122.
[16] Kagawa N,Matsuguchi A,Watanabe K.Measurements of Specific Heat Capacity of Gaseous R-143a Using aFlow Calorimeter[J].International Journal of Thermo.physics,2007,28(2): 481-489.
[17] Kagawa N,Matsuguchi A,Watanabe K.Measurement of Isobaric Heat Capacity of R125[J].International Journal of Refrigeration-Revue Internationale Du Froid, 2011,34(1): 275-279.
[18] Bhuiyan M M H,Hakin A W,Liu J L.Densities,Spe.cific Heat Capacities,Apparent and Partial Molar Vol.umes and Heat Capacities of Glycine in Aqueous Solu.tions of Formamide,Acetamide,and N,N-Dimethyl.acetamide at T=298.15K and Ambient Pressure[J].Journal of Solution Chemistry,2010,39(6): 877-896.
[19] Ernst G,Maurer G,Wiederuh E.Flow Calorimeter for the Accurate Determination of the Isobaric Heat Capaci.ty at High Pressure[J].Journal of Chemical Thormody.namics,1989,21(1).
[20] Hou L Y,Jia Z,Gong J S,et al.Heat Sink and Conver.sion of Catalytic Steam Reforming for Hydrocarbon Fuel[J].Journal of Propulsion and Power,2010,28(3): 453-457.
[21] Deng H W,Zhu K,Xu G Q,et al.Isobaric SpecificHeat Capacity Measurement for Kerosene RP-3 in theNear-Critical and Supercritical Regions[J].Journal of Chemical Engineering Data,2012,57: 263-268.* 收稿日期: 2017-08-11；修订日期: 2017-09-05。基金项目:青年科学基金项目( 21306147)；国家博士后科学基金项目( 2013M532044)。作者简介:贺宇锋,男,硕士生,研究领域为超临界条件下吸热型碳氢燃料热物理性质。 E-mail: 924134163@qq.com通讯作者:郭亚军,女,博士,副教授,研究领域为新型环保节能换热器研发、蒸汽发生器相变传热研究。 E-mail: 879400635@qq.com (编辑:史亚红)