Research Progress on Nanofluid Fuels Stability and Metal Particle Modification Methods

doi:10.13675/j.cnki.tjjs.190313

Journal of Propulsion Technology ›› 2020, Vol. 41 ›› Issue (3): 481-492.DOI: 10.13675/j.cnki.tjjs.190313

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Research Progress on Nanofluid Fuels Stability and Metal Particle Modification Methods

Institute of Thermal Energy Engineering，Zhejiang University，Hangzhou310027，China

Published:2021-08-15

纳米流体燃料稳定性及金属颗粒改性方法研究进展

伍婷婷¹,刘建忠¹,陈冰虹¹,杜龙金¹,杨卫娟¹

浙江大学热能工程研究所，浙江杭州310027

作者简介:伍婷婷，硕士生，研究领域为含能材料。E-mail：21827005@zju.edu.cn
基金资助:
国家自然科学基金（51876187）。

Abstract

Abstract: For the purpose of enhancing the stability of nanofluid fuels, scholars are seeking a more effective approach of metal particles modification. Development process of nanofluidic fuels as well as theoretical researches on its stability are briefly reviewed in the article, with focusing on the technical approaches to improve the stability of nanofluid fuels and the modification methods of metal particles. The stability mechanism of nanofuels is firstly introduced from two aspects: influencing factors and DLVO theory. The stability evaluation methods applied to nanofluid fuels are briefly described with that. After that, the preparation methods of nanofluid fuels are reported. In addition, it is pointed that using surfactants and surface modification of metal particles are principal means for improving the stability of nanofluid fuels and that surface modification of metal particles is an effective solution for both stability and combustion of nanofuels. Finally, after analyzing the related researches on the surface modification of boron and aluminum particles, the approaches and results of metal particles modification are summarized, and the future research trends are prospected.

摘要： 为提高纳米流体燃料的稳定性，探求更有效的金属颗粒改性方法，文中简要回顾了纳米流体燃料的发展历程和关于稳定性的理论研究，重点介绍了提高纳米流体燃料稳定性的技术途径和金属颗粒的改性方法，从影响因素和DLVO理论两方面介绍了纳米流体燃料的稳定性机理，简述了应用于纳米流体燃料的稳定性评价方法，报告了纳米流体燃料的制备方法。文中还指出，研究中采用添加表面活性剂和金属颗粒表面改性是提高纳米流体燃料稳定性的主要方法，其中金属颗粒表面改性是能同时解决纳米燃料稳定性和燃烧两方面问题的有效方法，通过分析硼、铝颗粒表面改性的相关研究，总结了金属颗粒改性方法及效果，对未来研究的趋势进行了展望。

关键词: 纳米流体燃料;稳定性;金属颗粒;表面改性;综述

WU Ting-ting¹,LIU Jian-zhong¹,CHEN Bing-hong¹,DU Long-jin¹,YANG Wei-juan¹. Research Progress on Nanofluid Fuels Stability and Metal Particle Modification Methods[J]. Journal of Propulsion Technology, 2020, 41(3): 481-492.

伍婷婷,刘建忠,陈冰虹,杜龙金,杨卫娟. 纳米流体燃料稳定性及金属颗粒改性方法研究进展[J]. 推进技术, 2020, 41(3): 481-492.

References

[1] Gibbs J B,Preston C NJr.Preparation and Physical Properties of Metal Slurry Fuels[R].Cleveland:Lewis Flight Propulsion Lab,1952.
[2] 鄂秀天凤，邹吉军，于开录.基于亲油性纳米颗粒的高密度悬浮燃料研究[D].天津:天津大学，2015.
[3] Mehta R N，Chakraborty M，Parikh P A.Nanofuels: Combustion， Engine Performance and Emissions [J].Fuel，2014，120:91-97.
[4] Klabunde K J，Stark J，Koper O，et al.Nanocrystals as Stoichiometric Reagents with Unique Surface Chemistry[J].Journal of Physical Chemistry，1996，100(30):12142-12153.
[5] Delogu F.Thermodynamics on the Nanoscale[J].Journal of Physical Chemistry B，2005，109(46):21938-21941.
[6] Berner M K，Zarko V E，Talawar M B.Nanoparticles of Energetic Materials: Synthesis and Properties (Review) [J].Combustion，Explosion， andShock Waves，2013，49(6):625–647.
[7] 宣益民.纳米流体能量传递理论与应用[M].北京:科学出版社，2010.
[8] Ojha P K，Karmakar S.Boron for Liquid Fuel Engines-A Review on Synthesis， Dispersion Stability in Liquid Fuel， and Combustion Aspects[J].Progress in Aerospace Sciences，2018，100:18-45.
[9] Basu S，Miglani A.Combustion and Heat Transfer Characteristics of Nanofluid Fuel Droplets: A Short Review[J].International Journal of Heat and Mass Transfer，2016，96:482-503.
[10] Agarwal D K，Vaidyanathan A，Sunil K S.Synthesis and Characterization of Kerosene-Alumina Nanofluids[J].Applied Thermal Engineering，2013，60(1):275-284.
[11] Ohshima，Hiroyuki，Makino Kimiko.Colloid and Interface Science in Pharmaceutical Research and Development[M].Amsterdom:Elsevier，2014.
[12] Xiu-T-F E，Zhang Y，Zou J J，et al.Oleylamine-Protected Metal (Pt， Pd) Nanoparticles for Pseudohomogeneous Catalytic Cracking of JP-10 Jet Fuel[J].Industrial & Engineering Chemistry Research，2014，53(31).
[13] Xiu-T-F E，Zhi X，Zhang X，et al.Ignition and Combustion Performances of High-Energy-Density Jet Fuels Catalyzed by Pt and Pd Nanoparticles[J].Energy & Fuels，2018，32(2):2163-2169.
[14] Chen B H，Liu J Z，Yao F，et al.Effect of Oleic Acid on the Stability and Rheology of Nanoaluminium/JP-10 Bi-Phase System[J].Micro & Nano Letters，2017，12(9):675-679.
[15] Li Y，Zhou J，Tung S，et al.A Review on Development of Nanofluid Preparation and Characterization[J].Powder Technology，2009，196(2):89-101.
[16] Ghadimi A，Saidur R，Metselaar H S C.A Review of Nanofluid Stability Properties and Characterization in Stationary Conditions[J].International Journal of Heat and Mass Transfer，2011，54(17-18):4051-4068.
[17] 王方，邹吉军.有机包覆的纳米铝颗粒制备及在碳氢燃料中的分散性研究[D].天津:天津大学，2016.
[18] Yu F，Chen Y，Liang X，et al.Dispersion Stability of Thermal Nanofluids[J].Progress in Natural Science: Materials International，2017，27(5):531-542.
[19] Shariatmadar F S，Pakdehi S G.Synthesis and Characterization of Aviation Turbine Kerosene Nanofuel Containing Boron Nanoparticles[J].Applied Thermal Engineering，2017，112:1195-1204.
[20] Chen B H，Liu J Z，Yuan J F，et al.Adsorption Behaviour of Tween 85 on Nano-Aluminium Particles in Aluminium/JP-10 Suspensions[J].Journal of Nanoscience and Nanotechnology，2019，19(4):2108-2115.
[21] Hiemenz P C，Rajagopalan R.Principles of Colloid and Surface Chemistry， Revised and Expanded[M].Boca Raton:CRC Press，1997.
[22] Ilyas S U，Pendyala R，Marneni N.Sedimentation， and Agglomeration of Nanofluids[J].Chemical Engineering and Technology，2014，37(12):2011-2021.
[23] Prasad Yadav T，Manohar Yadav R，Pratap Singh D.Mechanical Milling: a Top Down Approach for the Synthesis of Nanomaterials and Nanocomposites[J].Nanoscience and Nanotechnology，2012，2(3):22-48.
[24] Paskevicius M，Webb J，Pitt M P，et al.Mechanochemical Synthesis of Aluminium Nanoparticles and Their Deuterium Sorption Properties to 2 kbar[J].Journal of Alloys and Compounds，2009，481(1-2):595-599.
[25] 宋怀兵，徐复铭，周伟良.纳米金属/炭复合材料的制备及表征[D].南京:南京理工大学，2007.
[26] Neeleshwar S，Chen Y Y，Wang C R，et al.Superconductivity in Aluminum Nanoparticles [J].Physica C: Superconductivity，2004，408:209-210.
[27] Gan Y，Lim Y S，Qiao L.Combustion of Nanofluid Fuels with the Addition of Boron and Iron Particles at Dilute and Dense Concentrations[J].Combustion and Flame，2012，159(4):1732-1740.
[28] Javed I，Baek S W，Waheed K，et al.Evaporation Characteristics of Kerosene Droplets with Dilute Concentrations of Ligand-Protected Aluminum Nanoparticles at Elevated Temperatures[J].Combustion and Flame，2013，160(12):2955-2963.
[29] Xiu-T-F E，Zhang L，Wang F，et al.Synthesis of Aluminum Nanoparticles as Additive to Enhance Ignition and Combustion of High Energy Density Fuels[J].Frontiers of Chemical Science and Engineering，2018，12(3):358-366.
[30] 何庆兵，李忠盛，吴护林，等.等离子喷涂ZrO₂基纳米涂层研究进展[J].兵器装备工程学报，2016，37(11):128-132.
[31] Yu W，Xie H Q.A Review on Nanofluids: Preparation， Stability Mechanisms， and Applications[J].Journal of Nanomaterials，2012, （1）：1-17.
[32] Smirnov V V，Kostritsa S A，Kobtsev V D，et al.Experimental Study of Combustion of Composite Fuel Comprisingn-Decane and Aluminum Nanoparticles[J].Combustion and Flame，2015，162(10):3554-3561.
[33] Balanta A，Godard C，Claver C.Pd Nanoparticles for C-C Coupling Reactions[J].Chemical Society Reviews，2011，40(10):4973-4985.
[34] Gan Y，Qiao L.Combustion Characteristics of Fuel Droplets with Addition of Nano and Micron-Sized Aluminum Particles[J].Combustion and Flame，2011，158(2):354-368.
[35] Xiu-T-F E，Zhi X，Zhang Y，et al.Jet Fuel Containing Ligand-Protecting Energetic Nanoparticles: A Case Study of Boron in JP-10[J].Chemical Engineering Science，2015，129:9-13.
[36] Mathe V L，Varma V，Raut S，et al.Enhanced Active Aluminum Content and Thermal Behaviour of Nano-Aluminum Particles Passivated During Synthesis Using Thermal Plasma Route[J].Applied Surface Science，2016，368:16-26.
[37] Haynes W M.CRC Handbook of Chemistry and Physics[M].Boca Raton:CRC Press，2014.
[38] 尹敦兵，陈铁重，丛培胜，等.基于JP-10与RP-3燃烧的数值模拟[J].海军航空工程学院学报，2008(3):276-280.
[39] 刘建忠，梁导伦，周禹男，等.硼颗粒点火燃烧特性研究进展[J].固体火箭技术，2017，40(5):573-582.
[40] 李辰芳.包覆硼粒子提高硼的燃烧效率[J].推进技术，1994,15(2):53-57.( LI Chen-fang.Coating Boron Particles to Increase the Combustion Efficiency of Boron Fuel [J].Journal of Propulsion Technology，1994,15(2):53-57.)
[41] Calcote H F，Gill R J，Berman C H，et al.Production and Coating of Pure Boron Powders[R].Princeton：Aerochem Research Labs Inc，1990.
[42] Liu T K，Shyu I M，Hsia Y S.Effect of Fluorinated Graphite on Combustion of Boron and Boron-Based Fuel-Rich Propellants[J].Journal of Propulsion and Power，1996，12(1):26-33.
[43] Van Devener B，Perez J P L，Jankovich J，et al.Oxide-Free， Catalyst-Coated， Fuel-Soluble， Air-Stable Boron Nanopowder as Combined Combustion Catalyst and High Energy Density Fuel[J].Energy and Fuels，2009，23(12):6111-6120.
[44] Liang D，Liu J，Chen B，et al.Improvement in Energy Release Properties of Boron-Based Propellant by Oxidant Coating[J].Thermochimica Acta，2016，638:58-68.
[45] 陈冰虹，刘建忠，梁导伦，等.氧化剂包覆硼颗粒对硼基推进剂点火燃烧特性的影响[J].含能材料，2016，24(8):774-780.
[46] 周禹男，刘建忠，王架皓，等.铝颗粒氧化机理与燃烧理论研究进展[J].兵器材料科学与工程，2017，40(2):122-129.
[47] 刘香翠，朱慧，张炜，等.纳米铝粉在煤油中的均分散技术[J].推进技术，2005，26(2):184-187.
[48] Kim D M，Baek S W，Yoon J.Ignition Characteristics of Kerosene Droplets with the Addition of Aluminum Nanoparticles at Elevated Temperature and Pressure[J].Combustion and Flame，2016，173:1339-1351.
[49] Fernando K A S，Smith M J，Harruff B A，et al.Sonochemically Assisted Thermal Decomposition of Alane N， N-Dimethylethylamine with Titanium (IV) Isopropoxide in the Presence of Oleic Acid to Yield Air-Stable and Size-Selective Aluminum Core-Shell Nanoparticles[J].The Journal of Physical Chemistry C，2008，113(2):500-503.
[50] Lee Y J，Lee C，Lee H M.Synthesis of Oxide-Free Aluminum Nanoparticles for Application to Conductive Film[J].Nanotechnology，2018，29(5).
[51] 鄂秀天凤，彭浩，邹吉军，等.含有纳米铝颗粒的高密度悬浮燃料研究[J].推进技术，2016，37(5):974-978.
[52] Xiu-T-F E，Pan L，Wang F，et al.Al-Nanoparticle-Containing Nanofluid Fuel: Synthesis， Stability， Properties， and Propulsion Performance[J].Industrial and Engineering Chemistry Research，2016，55(10):2738-2745.

Research Progress on Nanofluid Fuels Stability and Metal Particle Modification Methods

纳米流体燃料稳定性及金属颗粒改性方法研究进展

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