Synthesis of Copper Chromite/Graphene Nanocomposites and Its Characterization as Catalyst for AP

Journal of Propulsion Technology ›› 2015, Vol. 36 ›› Issue (8): 1257-1261.

• Material,Propellant and Fuel • Previous Articles Next Articles

Synthesis of Copper Chromite/Graphene Nanocomposites and Its Characterization as Catalyst for AP

National Special Superfine Powder Engineering Research Center，Nanjing University of Science and Technology，Nanjing 210094，China,National Special Superfine Powder Engineering Research Center，Nanjing University of Science and Technology，Nanjing 210094，China and National Special Superfine Powder Engineering Research Center，Nanjing University of Science and Technology，Nanjing 210094，China

Published:2021-08-15

CuCr2O4/石墨烯复合粒子的制备及其对AP的催化作用

刘环环,姜　炜,郝嘎子

南京理工大学国家特种超细粉体工程技术研究中心，江苏南京 210094,南京理工大学国家特种超细粉体工程技术研究中心，江苏南京 210094,南京理工大学国家特种超细粉体工程技术研究中心，江苏南京 210094

作者简介:刘环环(1988—)，女，硕士生，研究领域为纳米催化剂的制备及其催化性能的研究。

Abstract

Abstract: CuCr2O4/graphene composites were synthesized by two-step method with graphene as a carrier. The microstructure and morphology were confirmed by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The catalysis of CuCr2O4，CuCr2O4/graphene，graphene and the mixture of CuCr2O4 and graphene on thermal decomposition of AP was investigated by DSC. The results show that copper chromic nanoparticles are coated on graphene sheets, without apparent aggregation. CuCr2O4/graphene composites make the high temperature exothermic peak of ammonium perchlorate decrease by 60℃ and the apparent decomposition heat increase from 837 to 1188J/g. The catalytic propertie of CuCr2O4/graphene is superior to that of CuCr2O4, graphene and the mixture of CuCr2O4 and graphene.

Key words: Composite catalysts；Thermal decomposition of AP；Catalysis；Graphene

摘要： 以石墨烯为载体，采用两步法制备了CuCr2O4/石墨烯复合粒子，通过X射线衍射仪(XRD)、透射电子显微镜(TEM)对样品的结构及形貌进行了表征，并采用差示扫描量热仪(DSC)分别研究了CuCr2O4、CuCr2O4/石墨烯、石墨烯及CuCr2O4和石墨烯的混合物对AP的催化效果。结果表明，CuCr2O4纳米粒子较均匀地分布在石墨烯上，CuCr2O4/石墨烯复合粒子使AP高温分解峰温度降至382℃，降低了60℃，表观分解热增加了351J/g，达1188 J/g，其催化效果明显优于CuCr2O4、石墨烯及CuCr2O4和石墨烯的混合物。

关键词: 复合催化剂；AP热分解；催化；石墨烯

LIU Huan-huan,JIANG Wei,HAO Ga-zi. Synthesis of Copper Chromite/Graphene Nanocomposites and Its Characterization as Catalyst for AP[J]. Journal of Propulsion Technology, 2015, 36(8): 1257-1261.

刘环环,姜　炜,郝嘎子. CuCr2O4/石墨烯复合粒子的制备及其对AP的催化作用[J]. 推进技术, 2015, 36(8): 1257-1261.

References

[1] 洪伟良, 刘剑洪, 田德余, 等. 纳米催化剂的特性及其在固体推进剂中的应[J]. 飞航导弹, 2000(4): 43-45.
[2] Yanwu Zhu, Murali Shanthi, Weiwei Cai, et al. Graphene and Graphene Oxide: Synthesis, Properties, and Applications[J]. Advanced Materials, 2010, 22: 3906-3924.
[3] 刘建勋, 李凤生, 陈爱四, 等. 纳米Fe2O3的制备及其对AP热分解的催化作用[J]. 推进技术, 2006, 27(4): 381-384.(LIU Jian-xun, LI Feng-sheng, CHEN Ai-si, et al. Preparation of Fe2O3 Nanoparticles and Its Catalytic Effect on Thermal Decomposition of Ammonium Perchlorate(AP)[J]. Journal of Propulsion Technology, 2006, 27(4): 381-384.)
[4] Kawamoto A M, Pardini L C, Rezende L C. Synthesis of Copper Chromite Catalyst[J]. Aerospace Science and Technology, 2004(8): 591-598.
[5] Campos E A, Dutra R C L, Rezende L C, et al. Performance Evaluation of Commercial Copper Chromite as Burning Rate Catalyst for Solid Propellants[J]. Journal of Aerospace Technology and Management, 2010(2): 323-330.
[6] 杨毅, 刘宏英, 李凤生, 等. 过渡金属/稀土金属氧化物纳米粒子催化AP热分解研究[J]. 推进技术, 2006, 27(1): 92-96.(YANG Yi, LIU Hong-ying, LI Feng-sheng, et al. Nanometer Transitionmetal Oxide and Rare Oxide Catalysis on AP Thermal Decomposition[J]. Journal of Propulsion Technology, 2006, 27(1): 92-96.)
[7] Stroupe J D. An X-ray Diffraction Study of the Copper Chromites and of the Copper-Chromium Oxide Catalyst[J]. Journal of the American Chemical Society, 1949, 71: 569-572.
[8] Boldyreva A V. Effects of Spinels on the Pyrolysis and Combustion Rates for Ammonium Perchlorate Mixtures[J]. Combustion Explosion and Shock Waves, 1975, 11: 611-613.
[9] 张汝冰. 微乳液法制备亚铬酸铜[P]. 中国专利:CN 1426965A.
[10] Aparecida M Kawamoto, Luiz Claudio Pardini, Luis Claudio Rezende. Synthesis of Copper Chromite Catalyst[J]. Aerospace Science and Technology,2004,(8): 591-598.
[11] Wei Li, Hua Cheng. Cu-Cr-O Nanocomposites: Synthesis and Characterization as Catalysts for Solid State Propellants[J]. Solid State Sciences, 2007(9): 750-755.
[12] Sathiskumar P S, Thomas C R, Giridhar Madras. Solution Combustion Synthesis of Nanosized Copper Chromite and Its Use as Burn Rate Modifier in Solid Propellants[J]. Industrial & Engineering Chemistry Research, 2012, 51: 10108-10116.
[13] 李伟娜, 刘志红, 谢皓雪. 表面活性剂的结构特点及应用研究进展[J]. 长寿医药, 2008, 6(2): 68-70.
[14] Palaniselvam T, Aiyappa H B, Kurungot S. An Efficient Oxygen Reduction Electrocatalyst from Graphene by Simultaneously Generating Pores and Nitrogen Doped Active Sites[J]. Journal of Materials Chemistry, 2012, 22: 23799-23805.
[15] 王学宝, 李晋庆, 罗运军. 高氯酸铵/石墨烯纳米复合材料的制备及热分解行为[J]. 火炸药学报, 2012, 35(6): 76-80.
[16] Fitzgerald R, Brewster M. Flame and Surface Structure of Laminate Propellants with Coarse and Fine Ammonium Perchlorate[J]. Combustion and Flame, 2004, 136: 313-326.
[17] 刘子如, 阴翠梅, 孔扬辉, 等. 高氯酸铵的热分解[J]. 含能材料, 2000, 8(2): 75-79.
[18] Prajakta R Patil, Krishnamurthy V N, Satyawati S Joshi. Effect of Nano-Copper Oxide and Copper Chromite on the Thermal Decomposition of Ammonium Perchlorate[J]. Propellents,Explosives,Pyrotechnics, 2008, 33: 266-270.
[19] Freeman E S, Anderson D A. Effects of Radiation and Doping on the Catalytic Activity of Magnesium Oxide on the Thermal Decomposition of Potassium Perchlorate[J]. Nature, 1965, 206, 378.
[20] 云主惠, 周政懋. 热分解动力学数据分析[J]. 火炸药学报, 1982, (2): 34-37.(编辑:史亚红)　　　　　　　　　　　　　*　收稿日期:2014-05-20；修订日期:2014-07-11。作者简介:刘环环(1988—),女,硕士生,研究领域为纳米催化剂的制备及其催化性能的研究。E-mail: lh150208134@163.com

Synthesis of Copper Chromite/Graphene Nanocomposites and Its Characterization as Catalyst for AP

CuCr2O4/石墨烯复合粒子的制备及其对AP的催化作用

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 0

Recommended Articles

Metrics

Comments