Effects of Oxygen Concentration on Ignition and Combustion Characteristics of Zirconium Powder
LIU Qing
1,CHEN Lin-quan
1,ZHOU Yu-nan
2,YUAN Ji-fei
2,WANG Jian-ru
1,LIU Jian-zhong
2
To study the effects of oxygen concentration on the ignition performance of zirconium powder, the combustion process of zirconium powder was observed by CO
2 laser ignition bench, high-speed camera, two-color infrared thermometer and fiber optic spectrometer. The ignition delay time, combustion time, combustion intensity and combustion temperature parameters during the combustion of zirconium powder were obtained. Subsequently, the phase characteristics of the combustion products were analyzed by XRD. It is known from the experimental results that the combustion process of zirconium powder can be divided into four stages: lighting, intense combustion, stable combustion and flame extinction according to the flame shape. The oxygen concentration has an important influence on the ignition and combustion performance of zirconium powder. The ignition delay times of zirconium powder in the four working conditions of C1~C4 are 15ms, 17.5ms, 22.5ms and 25ms, respectively. The combustion temperatures are 1542℃, 1520℃, 1425℃ and 1405℃, respectively. Therefore, increasing the oxygen concentration is beneficial to shorten the ignition delay time and combustion time, increase the combustion temperature and combustion intensity, and improve the ignition and combustion performance of the zirconium powder. As the oxygen concentration increases, the flame size, flame brightness and combustion intensity show an increasing trend. At the same time, it was found that the main phase of the combustion product of zirconium powder at four different oxygen concentrations is ZrO
2, and no phase such as ZrN and ZrC is produced.